Ontology highlight
ABSTRACT:
SUBMITTER: Quasdorf KW
PROVIDER: S-EPMC3091075 | biostudies-literature | 2011 Apr
REPOSITORIES: biostudies-literature
Journal of the American Chemical Society 20110401 16
The first Suzuki-Miyaura cross-coupling reactions of the synthetically versatile aryl O-carbamate and O-sulfamate groups are described. The transformations utilize the inexpensive, bench-stable catalyst NiCl(2)(PCy(3))(2) to furnish biaryls in good to excellent yields. A broad scope for this methodology has been demonstrated. Substrates with electron-donating and electron-withdrawing groups are tolerated, in addition to those that possess ortho substituents. Furthermore, heteroaryl substrates ma ...[more]