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Bis(3-hy-droxy-methyl-anilinium) hexa-chloridostannate(IV).

ABSTRACT: In the title compound, (C(7)H(10)NO)(2)[SnCl(6)], the Sn(IV) atom, located on an inversion center, exists in an octa-hedral coordination environment. The crystal structure exhibits alternating organic and inorganic layers parallel to ([Formula: see text]01). The cations and anions are linked via inter-molecular N-H?O, N-H?Cl and O-H?Cl hydrogen bonds. Additional stabilization is provided by ?-? stacking inter-actions between the benzene rings of the cations [centroid-centroid distances = 3.6962?(15) and 3.9340?(15)?Å].

SUBMITTER: Bouacida S

PROVIDER: S-EPMC3099789 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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Bis(3-hy-droxy-methyl-anilinium) hexa-chloridostannate(IV).

Bouacida Sofiane S Kechout Habiba H Belhouas Ratiba R Merazig Hocine H Roisnel Thierry T

Acta crystallographica. Section E, Structure reports online 20110302 Pt 4

In the title compound, (C(7)H(10)NO)(2)[SnCl(6)], the Sn(IV) atom, located on an inversion center, exists in an octa-hedral coordination environment. The crystal structure exhibits alternating organic and inorganic layers parallel to ([Formula: see text]01). The cations and anions are linked via inter-molecular N-H⋯O, N-H⋯Cl and O-H⋯Cl hydrogen bonds. Additional stabilization is provided by π-π stacking inter-actions between the benzene rings of the cations [centroid-centroid distances = 3.6962 ...[more]

PMID: 21753931

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