Browse
Submit Data
Databases
API
Help

Dataset Information

17 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

{2-(4-Hy-droxy-phen-yl)-2-[(3-meth-oxy-2-oxidobenzyl-idene)amino-κO,N]propanoato-κO}(1,10-phenanthroline-κN,N')copper(II) dihydrate.

ABSTRACT: In the title complex, [Cu(C(17)H(15)NO(5))(C(12)H(8)N(2))]·2H(2)O, the central Cu(II) ion is five-coordinate, bound to one N atom and two O atoms from the Schiff base ligand and by two N atoms from a 1,10-phenanthroline ligand in a distorted square-pyramidal configuration. In the crystal, inter-molecular O-H⋯O and C-H⋯O hydrogen bonds form a two-dimensional network parallel to (001).

SUBMITTER: Pu X

PROVIDER: S-EPMC3099980 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Bis(4'-hy-droxy-biphenyl-4-carboxyl-ato-κO)(1,10-phenanthroline-κN,N')zinc.

Project description:In the title compound, [Zn(C(13)H(9)O(3))(2)(C(12)H(8)N(2))], the Zn(II) atom is located on a twofold rotation axis and has a distorted tetra-hedral coordination with two N atoms from the phenanthroline ligand arranged around the twofold axis and two O atoms from two symmetry-related 4'-hy-droxy-biphenyl-4-carboxyl-ate ligands. The mol-ecules are linked by O-H⋯O hydrogen bonds, forming a chain developing parallel to [101].

| S-EPMC3089091 | biostudies-literature

Aqua-bis-(4-chloro-2-hy-droxy-benzoato-κO)(1,10-phenanthroline-κN,N')zinc(II).

Project description:In the title compound, [Zn(C(7)H(4)ClO(3))(2)(C(12)H(8)N(2))(H(2)O)], the Zn(II) cation is coordinated by two 4-chloro-2-salicylate anions, one 1,10-phenanthroline ligand and one water mol-ecule in a square-pyramidal coordination geometry; the Zn cation lies 0.4591 (11) Å from the basal plane. The benzene rings of the anions are involved in π-π stacking. The centroid-centroid distance between parallel benzene rings of adjacent mol-ecules is 3.9017 (17) Å, and the centroid-centroid distance between benzene and pyridine rings of adjacent mol-ecules is 3.584 (2) Å. Intra-molecular O-H⋯O hydrogen bonding is present.

| S-EPMC3151932 | biostudies-literature

Bis(μ-2,4-dihy-droxy-benzoato-κO:O')bis-[aqua-(2,4-dihy-droxy-benzoato-κO)(1,10-phenanthroline-κN,N')cadmium(II)].

Project description:In the title centrosymmetric dimeric Cd(II) complex, [Cd(2)(C(7)H(5)O(4))(4)(C(12)H(8)N(2))(2)(H(2)O)(2)], the Cd(II) cation is coord-inated by a bidentate phenanthroline (phen) ligand, three dihy-droxy-benzoate (dhba) anions and one water mol-ecule in a distorted CdN(2)O(4) octa-hedral geometry. Among the dhba anions, two anions bridge two Cd(II) cations to form the dimeric complex with significant different Cd-O bond distances of 2.2215 (19) and 2.406 (2) Å. The centroid-centroid distance of 3.4615 (19) Å between two nearly parallel benzene rings of the dhba and phen ligands coordinating to the same Cd(II) cation indicates the existence of intra-molecular π-π stacking in the complex. Extensive O-H⋯O hydrogen bonding and inter-molecular weak C-H⋯O hydrogen bonding help to stabilize the crystal structure. One hy-droxy group of the monodentate dhba ligand is disordered over two sites with a site-occupancy ratio of 0.9:0.1.

| S-EPMC3006915 | biostudies-literature

Aqua-(2,9-dimethyl-1,10-phenanthroline-κN,N')diformato-κO,O';κO-nickel(II) monohydrate.

Project description:The asymmetric unit of the title compound, [Ni(HCO(2))(2)(C(14)H(12)N(2))(H(2)O)]·H(2)O, contains a mononuclear complex mol-ecule hydrogen bonded to a lattice water mol-ecule. The Ni(II) atom exhibits a distorted octa-hedral coordination geometry formed by the N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand, two O atoms of a chelating formate anion, one aqua O atom and one O atom of a coordinating formate anion. The mol-ecules are assembled into chains extending along [100] through by O-H⋯O hydrogen bonds. The supra-molecular chains are further linked into layers parallel to (011) by weak π-π packing inter-actions [centroid-centroid separation = 3.768 (2) Å]. The resulting layers are stacked to meet the requirement of close-packing patterns.

| S-EPMC3200966 | biostudies-literature

catena-Poly[[(nitrato-κO)(1,10-phenanthroline-κN,N')manganese(II)]-μ-nitrato-κO:O'].

Project description:In the crystal structure of the title compound, [Mn(NO(3))(2)(C(12)H(8)N(2))](n), the Mn(II) atoms are linked by nitrate ligands to form a chain. Each Mn(II) atom is five-coordinated by two N atoms of a 1,10-phenanthroline ligand and three O atoms of two nitrates within a trigonal-bipyramidal coordination geometry. In the crystal structure, the chains are linked by hydrogen bonds into a polymeric ribbon structure.

| S-EPMC2914918 | biostudies-literature

Tris(nitrato-κO,O')bis-(1,10-phenanthroline-κN,N')holmium(III).

Project description:In the title compound, [Ho(NO(3))(3)(C(12)H(8)N(2))(2)], the ten-coordinate Ho(III) ion is chelated by four N atoms from two phenanthroline (phen) ligands and six O atoms from three bidentate nitrate groups. The environment around the Ho atom can be described as a distorted bicapped square anti-prism. Two phenanthroline ligands form a dihedral angle of 43.72 (13)°. Short inter-molecular distances between the centroids of the six-membered rings [3.6887 (14)-3.8374 (16) Å] indicate the existence of π-π inter-actions, which link the mol-ecules into stacks extended in the [10] direction. The crystal packing is further stabilized by weak inter-molecular C-H⋯O hydrogen bonds.

| S-EPMC2961938 | biostudies-literature

Bis(3,5-dicarboxy-benzoato-κO,O')(1,10-phenanthroline-κN,N')cadmium(II).

Project description:The mol-ecule of the title compound, [Cd(C(9)H(5)O(6))(2)(C(12)H(8)N(2))], has crystallographic twofold rotation symmetry. The Cd(II) atom, located on the twofold axis, assumes a CdO(4)N(2) distorted octa-hedral coordination geometry. In the crystal structure, the mol-ecules link to each other by O-H⋯O and C-H⋯O hydrogen bonding to form a three-dimensional supra-molecular network.

| S-EPMC2914923 | biostudies-literature

catena-Poly[[(1,10-phenanthroline-κN,N')praseodymium(III)]-di-μ-phenoxy-acetato-κO:O'-[(1,10-phenanthroline-κN,N')praseodymium(III)]-di-μ-phenoxy-acetato-κO:O'-di-μ-phenoxy-acetato-κO,O':O;κO:O,O'].

Project description:The title complex, [Pr(2)(C(8)H(7)O(3))(6)(C(12)H(8)N(2))(2)](n), which has an inversion centre midway between the two Pr(III) atoms of the structural unit, forms a one-dimensional polymer bridged alternately by either two bidentate, or two bidentate and two terdentate, phenoxy-acetate carboxyl-ate groups. Each Pr(III) atom is thus nine-coordinated by two N atoms of a 1,10-phenanthroline ligand and seven O atoms from six phenoxy-acetate ligands. The coordination geometry at the Pr(III) atom is distorted tricapped trigonal prismatic. One phenyl ring is disordered over two positions; the site occupancy factors are ca 0.6 and 0.4.

| S-EPMC2960179 | biostudies-literature

Aqua-(imino-diacetato-κO,N,O')(1,10-phenanthroline-κN,N')zinc(II) sesquihydrate.

Project description:The imino-diacetate dianion in the title compound, [Zn(C(4)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)]·1.5H(2)O, chelates to the Zn(II) center with its N and two O atoms. The metal atom is also chelated by the N-heterocycle and coordinated by one water molecule, leading to a distorted octahedral environment. The dianion, and coordinated and uncoordinated water mol-ecules inter-act through O-H⋯O hydrogen bonds, generating a three-dimensional network. One of the two uncoordinated water mol-ecules has half-site occupancy. The crystal studied was a non-merohedral twin with a 15% twin component.

| S-EPMC2967921 | biostudies-literature

Bis(2,9-dimethyl-1,10-phenanthroline-κN,N')bis-(nitrato-κO,O')lead(II).

Project description:In the title complex, [Pb(NO(3))(2)(C(14)H(12)N(2))(2)], the lead ion is chelated by two 2,9-dimethyl-1,10-phenanthroline (dmphen) ligands and two nitrate anions in a slightly distorted square-anti-prismatic geometry. Intra- and inter-molecular π-π stacking is present in the crystal structure, and the centroid-centroid distances between the benzene and pyridine rings of adjacent dmphen ligands are 3.492 (3) and 3.592 (3) Å, respectively. Inter-molecular C-H⋯O hydrogen bonds and C-H⋯π inter-actions help to stabilize the crystal structure.

| S-EPMC3006962 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data