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Poly[[[silver(I)-?-1,4-bis-[(imidazol-1-yl)meth-yl]benzene-?N:N-silver(I)-?-1,4-bis-[(imidazol-1-yl)meth-yl]benzene-?N:N] 4,4'-diazenediyldibenzoate] dihydrate].

ABSTRACT: In the title compound, [Ag(2)(C(14)H(14)N(4))(2)](C(14)H(8)N(2)O(4))·2H(2)O, each of the two unique Ag(+) ions is two-coordinated by two N atoms from two different 1,4-bis-[(imidazol-1-yl)meth-yl]benzene ligands in an almost linear fashion [N-Ag-N = 170.34?(10) and 160.25?(10)°]. The 4,4'-diazenediyldibenzoate anions do not coordinate to Ag. O-H?O hydrogen bonds stabilize the crystal structure.

SUBMITTER: Qiao Q 

PROVIDER: S-EPMC3100071 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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Poly[[[silver(I)-μ-1,4-bis-[(imidazol-1-yl)meth-yl]benzene-κN:N-silver(I)-μ-1,4-bis-[(imidazol-1-yl)meth-yl]benzene-κN:N] 4,4'-diazenediyldibenzoate] dihydrate].

Qiao Qian Q   Tian Mei M   Liu Da-Yong DY   Wang Shu-Jiang SJ  

Acta crystallographica. Section E, Structure reports online 20110323 Pt 4

In the title compound, [Ag(2)(C(14)H(14)N(4))(2)](C(14)H(8)N(2)O(4))·2H(2)O, each of the two unique Ag(+) ions is two-coordinated by two N atoms from two different 1,4-bis-[(imidazol-1-yl)meth-yl]benzene ligands in an almost linear fashion [N-Ag-N = 170.34 (10) and 160.25 (10)°]. The 4,4'-diazenediyldibenzoate anions do not coordinate to Ag. O-H⋯O hydrogen bonds stabilize the crystal structure. ...[more]

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