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(E)-[({[(3-Methyl-phen-yl)meth-yl]sulfan-yl}methane-thio-yl)amino](1-phenyl-pentyl-idene)amine.

ABSTRACT: In the structure of the title compound, C(20)H(24)N(2)S(2), the central CN(2)S(2) atoms are planar (r.m.s. deviation = 0.0205?Å) but both benzene rings are twisted out of this plane forming dihedral angles of 23.03?(6) and 84.75?(4)° (tol-yl); the n-butyl group occupies a position normal to the plane [N-C-C-C torsion angle = -84.33?(16)°]. The conformation of the imine bond [1.2888?(18)?Å] is E. The syn arrangement of the thione S and amino H atoms enables the formation of N-H?S hydrogen bonds between centrosymmetrically related mol-ecules. These lead to eight-membered {?HNC=S}(2) synthons which are further stabilized by proximate C-H?S interactions. The resulting dimeric aggregates are connected into a supra-molecular chain along the c axis by C-H??(tol-yl) inter-actions.

SUBMITTER: Paulus G

PROVIDER: S-EPMC3120291 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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(E)-[({[(3-Methyl-phen-yl)meth-yl]sulfan-yl}methane-thio-yl)amino](1-phenyl-pentyl-idene)amine.

Paulus Georgiana G Crouse Karen A KA Mohamed Tahir Mohamed Ibrahim MI Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20110511 Pt 6

In the structure of the title compound, C(20)H(24)N(2)S(2), the central CN(2)S(2) atoms are planar (r.m.s. deviation = 0.0205 Å) but both benzene rings are twisted out of this plane forming dihedral angles of 23.03 (6) and 84.75 (4)° (tol-yl); the n-butyl group occupies a position normal to the plane [N-C-C-C torsion angle = -84.33 (16)°]. The conformation of the imine bond [1.2888 (18) Å] is E. The syn arrangement of the thione S and amino H atoms enables the formation of N-H⋯S hydrogen bonds b ...[more]

PMID: 21754762

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