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N-(4-Fluoro-benz-yl)-3-nitro-pyridine-2,6-diamine.

ABSTRACT: In the title compound, C(12)H(11)FN(4)O(2), the pyridine ring is connected to a benzene ring by a -CH(2)-NH(2)- chain. The nitro group is twisted out of the pyridine ring plane [torsion angle O-N-C-C = 10.41?(10)°]. An intramolecular N-H?O hydrogen bond occurs. The fluoro-benzene ring is disordered over two positions [occupancy ratio = 0.59?(3):0.41?(3)]. Inter-molecular N-H?O and N-H?N hydrogen bonds stabilize the crystal structure.

SUBMITTER: Ge JL

PROVIDER: S-EPMC3120364 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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N-(4-Fluoro-benz-yl)-3-nitro-pyridine-2,6-diamine.

Ge Ji-Long JL Qian Xiao-Min XM

Acta crystallographica. Section E, Structure reports online 20110520 Pt 6

In the title compound, C(12)H(11)FN(4)O(2), the pyridine ring is connected to a benzene ring by a -CH(2)-NH(2)- chain. The nitro group is twisted out of the pyridine ring plane [torsion angle O-N-C-C = 10.41 (10)°]. An intramolecular N-H⋯O hydrogen bond occurs. The fluoro-benzene ring is disordered over two positions [occupancy ratio = 0.59 (3):0.41 (3)]. Inter-molecular N-H⋯O and N-H⋯N hydrogen bonds stabilize the crystal structure. ...[more]

PMID: 21754850

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