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Diiodidobis[4-(4-nitro-benz-yl)pyridine-?N]zinc.

ABSTRACT: The asymmetric unit of the title compound, [ZnI(2)(C(12)H(10)N(2)O(2))(2)], obtained from the reaction of 4-(4-nitro-benz-yl)pyridine with zinc(II) iodide, contains two independent discrete distorted tetra-hedral complex units [Zn-I = 2.5472?(8)-2.5666?(7)?Å and Zn-N = 2.044?(4)-2.052?(4)?Å], which are essentially identical conformationally. The crystal used for measurement was a racemic twin.

SUBMITTER: Smith G

PROVIDER: S-EPMC3052165 | biostudies-literature | 2011

REPOSITORIES: biostudies-literature

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Diiodidobis[4-(4-nitro-benz-yl)pyridine-κN]zinc.

Smith Graham G Wermuth Urs D UD Williams Michael L ML

Acta crystallographica. Section E, Structure reports online 20110223 Pt 3

The asymmetric unit of the title compound, [ZnI(2)(C(12)H(10)N(2)O(2))(2)], obtained from the reaction of 4-(4-nitro-benz-yl)pyridine with zinc(II) iodide, contains two independent discrete distorted tetra-hedral complex units [Zn-I = 2.5472 (8)-2.5666 (7) Å and Zn-N = 2.044 (4)-2.052 (4) Å], which are essentially identical conformationally. The crystal used for measurement was a racemic twin. ...[more]

PMID: 21522285

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