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Catena-Poly[[[bis-(3-hy-droxy-adamantane-1-carboxyl-ato-?O)(3-hy-droxy-adamantane-1-carb-oxy-lic acid-?O)zinc(II)]-?(2)-4,4'-bipyridine] monohydrate].

ABSTRACT: In the title coordination polymer, {[Zn(C(11)H(15)O(3))(2)(C(10)H(8)N(2))(C(11)H(16)O(3))]·H(2)O}(n), the Zn(II) ion is five coordinated by two N atoms from two 4,4'-bipyridine (4,4'-bpy) mol-ecules and three O atoms from two 3-hy-droxy-adamantane-1-carboxyl-ate anions (L) and one 3-hy-droxy-adamantane-1-carb-oxy-lic acid (HL) mol-ecule. The resulting coordination polyhedron is a near regular ZnN(2)O(3) trigonal bipyramid, with the N atoms in axial sites. The 4,4'-bpy mol-ecules [dihedral angle between the aromatic rings = 17.2?(2)°] act as bridges, connecting the metal ions into an infinite polymeric chain propagating in [[Formula: see text]01]. O-H?O hydrogen bonds help to consolidate the packing.

SUBMITTER: Shen JB 

PROVIDER: S-EPMC3120402 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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catena-Poly[[[bis-(3-hy-droxy-adamantane-1-carboxyl-ato-κO)(3-hy-droxy-adamantane-1-carb-oxy-lic acid-κO)zinc(II)]-μ(2)-4,4'-bipyridine] monohydrate].

Shen Jin-Bei JB   Guan Quan-Yin QY   Chen Xiao-Ju XJ   Zhao Guo-Liang GL  

Acta crystallographica. Section E, Structure reports online 20110507 Pt 6

In the title coordination polymer, {[Zn(C(11)H(15)O(3))(2)(C(10)H(8)N(2))(C(11)H(16)O(3))]·H(2)O}(n), the Zn(II) ion is five coordinated by two N atoms from two 4,4'-bipyridine (4,4'-bpy) mol-ecules and three O atoms from two 3-hy-droxy-adamantane-1-carboxyl-ate anions (L) and one 3-hy-droxy-adamantane-1-carb-oxy-lic acid (HL) mol-ecule. The resulting coordination polyhedron is a near regular ZnN(2)O(3) trigonal bipyramid, with the N atoms in axial sites. The 4,4'-bpy mol-ecules [dihedral angle  ...[more]

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