Unknown

Dataset Information

0

Catena-Poly[[[bis-(3-hy-droxy-adamantane-1-carboxyl-ato-?O)(3-hy-droxy-adamantane-1-carb-oxy-lic acid-?O)zinc(II)]-?(2)-4,4'-bipyridine] monohydrate].

ABSTRACT: In the title coordination polymer, {[Zn(C(11)H(15)O(3))(2)(C(10)H(8)N(2))(C(11)H(16)O(3))]·H(2)O}(n), the Zn(II) ion is five coordinated by two N atoms from two 4,4'-bipyridine (4,4'-bpy) mol-ecules and three O atoms from two 3-hy-droxy-adamantane-1-carboxyl-ate anions (L) and one 3-hy-droxy-adamantane-1-carb-oxy-lic acid (HL) mol-ecule. The resulting coordination polyhedron is a near regular ZnN(2)O(3) trigonal bipyramid, with the N atoms in axial sites. The 4,4'-bpy mol-ecules [dihedral angle between the aromatic rings = 17.2?(2)°] act as bridges, connecting the metal ions into an infinite polymeric chain propagating in [[Formula: see text]01]. O-H?O hydrogen bonds help to consolidate the packing.

SUBMITTER: Shen JB 

PROVIDER: S-EPMC3120402 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

catena-Poly[[[bis-(3-hy-droxy-adamantane-1-carboxyl-ato-κO)(3-hy-droxy-adamantane-1-carb-oxy-lic acid-κO)zinc(II)]-μ(2)-4,4'-bipyridine] monohydrate].

Shen Jin-Bei JB   Guan Quan-Yin QY   Chen Xiao-Ju XJ   Zhao Guo-Liang GL  

Acta crystallographica. Section E, Structure reports online 20110507 Pt 6

In the title coordination polymer, {[Zn(C(11)H(15)O(3))(2)(C(10)H(8)N(2))(C(11)H(16)O(3))]·H(2)O}(n), the Zn(II) ion is five coordinated by two N atoms from two 4,4'-bipyridine (4,4'-bpy) mol-ecules and three O atoms from two 3-hy-droxy-adamantane-1-carboxyl-ate anions (L) and one 3-hy-droxy-adamantane-1-carb-oxy-lic acid (HL) mol-ecule. The resulting coordination polyhedron is a near regular ZnN(2)O(3) trigonal bipyramid, with the N atoms in axial sites. The 4,4'-bpy mol-ecules [dihedral angle  ...[more]

Similar Datasets

Unknown Poly[[?-aqua-bis-(?-4,4'-bipyridine-?N:N')bis-(?-3-hy-droxy-adamantane-1-carboxyl-ato-?O:O')bis-(3-hy-droxy-adamantane-1-carboxyl-ato-?O)dicobalt(II)] hepta-hydrate].
| S-EPMC3089202 | biostudies-literature
Unknown catena-Poly[[(tetra-aqua-cadmium)-?-4,4'-bipyridine-?(2)N:N'] 4-hy-droxy-3-sulfonato-benzoate monohydrate].
| S-EPMC3379062 | biostudies-literature
Unknown ?-4,4'-Bipyridine-bis-[aqua-(4-hy-droxy-pyridine-2,6-dicarboxyl-ato)copper(II)].
| S-EPMC3297272 | biostudies-literature
Unknown catena-Poly[[[aqua-(5-carb-oxy-pyridine-3-carboxyl-ato-?N)copper(I)]-?-4,4'-bipyridine-?N:N'] monohydrate].
| S-EPMC3274861 | biostudies-other
Unknown 4,4'-Bipyridine-cyclo-hexane-1,2,4,5-tetra-carb-oxy-lic acid (1/1).
| S-EPMC3009091 | biostudies-literature
Unknown 4,4'-Bipyridine-2-(carb-oxy-methyl-sulfan-yl)pyridine-3-carb-oxy-lic acid (1/1).
| S-EPMC3011421 | biostudies-literature
Unknown 5-(Hy-droxy-meth-yl)furan-2-carb-oxy-lic acid.
| S-EPMC3120284 | biostudies-literature
Unknown catena-Poly[[{diaqua-[2-(4-hy-droxy-phen-yl)acetato-κO,O']cerium(III)}-bis-[μ-2-(4-hy-droxy-phen-yl)acetato]-κO,O':O;κO:O,O'] 4,4'-bipyridine disolvate monohydrate].
| S-EPMC3011412 | biostudies-literature
Unknown Biphenyl-2,2',4,4'-tetra-carb-oxy-lic acid monohydrate.
| S-EPMC2983381 | biostudies-other
Unknown catena-Poly[[bis-(3,5-dicarboxy-benzo-ato)cobalt(II)]-μ-4,4'-bipyridine].
| S-EPMC2959783 | biostudies-literature