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Catena-Poly[bis-(?(3)-2-methyl-benzoato)disilver(I)].

ABSTRACT: The crystal structure of the title compound, [Ag(2)(C(8)H(7)O(2))(2)](n), features polymeric chains extending along the a axis, with the two Ag(+) cations in a distorted trigonal coordination. The range of Ag-O bond lengths is 2.169?(2)-2.433?(2)?Å, whereas the Ag?Ag separations are in the range 2.8674?(4)-3.6256?(5)?Å. The 2-methyl-benzoate groups are oriented at a dihedral angle of 60.7?(1)° with respect to each other.

SUBMITTER: Danish M

PROVIDER: S-EPMC3120433 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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catena-Poly[bis-(μ(3)-2-methyl-benzoato)disilver(I)].

Danish Muhammad M Tahir M Nawaz MN Ghafoor Sabiha S Ahmad Nazir N Nisa Mehwish M

Acta crystallographica. Section E, Structure reports online 20110507 Pt 6

The crystal structure of the title compound, [Ag(2)(C(8)H(7)O(2))(2)](n), features polymeric chains extending along the a axis, with the two Ag(+) cations in a distorted trigonal coordination. The range of Ag-O bond lengths is 2.169 (2)-2.433 (2) Å, whereas the Ag⋯Ag separations are in the range 2.8674 (4)-3.6256 (5) Å. The 2-methyl-benzoate groups are oriented at a dihedral angle of 60.7 (1)° with respect to each other. ...[more]

PMID: 21754629

Similar Datasets

catena-Poly[bis-(?(3)-2-methyl-3,5-dinitro-benzoato)disilver(I)].

Project description:In the title coordination polymer, [Ag(2)(C(8)H(5)N(2)O(6))(2)](n), the silver ion is coordinated to three O atoms from three different anions in an approximate T-shape with one bond much longer than the other two. The polyhedral connectivity leads to [100] chains containing alternating centrosymmetric four-rings and eight-rings, with a short d(10)?d(10) Ag?Ag interaction [2.8846?(4)?Å] across the latter. The nitro groups are oriented at dihedral angles of 21.2?(5) and 64.3?(3)° with respect to the aromatic ring of the ligand. A C-H?O inter-action occurs in the crystal.

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catena-Poly[(diaqua-strontium)-bis-(μ-2-methyl-3,5-dinitro-benzoato)].

Project description:The title compound, [Sr(C(8)H(5)N(2)O(6))(2)(H(2)O)(2)](n), essentially consists of a one-dimensional polymeric network with Sr(2)O(2) rings extending along the [100] direction. The range of Sr-O bond lengths is 2.4822 (13)-2.8113 (13) Å. C-H⋯O and O-H⋯O hydrogen-bonding inter-actions stabilize the mol-ecules in the form of a two-dimensional polymeric network parallel to (001). One of the nitro groups is disordered over three sets of sites with the occupancy ratio of 0.46:0.32:0.22.

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catena-Poly[[bis-(3-methyl-benzoato-?O,O')lead(II)]-?-4,4'-bipyridine-?N:N'].

Project description:In the title complex, [Pb(C(8)H(7)O(2))(2)(C(10)H(8)N(2))](n), the Pb(II) atom is located on a twofold rotation axis and is six-coordinated by four carboxyl-ate O atoms from two 3-methyl-benzoate ligands and two N atoms from two 4,4'-bipyridine (4,4'-bpy) ligands, displaying a hemi-directed coordination. The 4,4'-bpy ligand has an inversion center at the mid-point of the central C-C bond. The Pb(II) atoms are linked by bidentate bridging 4,4'-bpy into a chain along [101]. These chains are further connected into layers via C-H?O hydrogen bonds.

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catena-Poly[[bis-(4-methyl-benzoato-κO:O')lead(II)]-μ-nicotinamide-κN:O].

Project description:In the title compound, [Pb(C(8)H(7)O(2))(2)(C(6)H(6)N(2)O)](n), the Pb(II) ion is coordinated by two 4-methyl-benzoate (PMB) and one nicotinamide (NA) ligands while symmetry-related NA ligands bridge adjacent Pb(II) ions, forming polymeric chains along the c axis. The carboxyl-ate groups in the two PMB ions are twisted away from the attached benzene ring by 22.9 (2) and 4.6 (2)°. The two benzene rings of the PMB ions are oriented at a dihedral angle of 83.7 (1)°. In a polymeric chain, the NA ligands are linked to PMB ions through intra-molecular N-H⋯O hydrogen bonds. In the crystal structure, adjacent polymeric chains inter-act via N-H⋯O and C-H⋯O hydrogen bonds, forming a two-dimensional network parallel to the bc plane.

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catena-Poly[bis-(μ-4-methyl-benzoato-κO:O')hepta-kis(μ-4-methyl-benzoato-κO,O':O)tris-amarium(III)].

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catena-Poly[[(4-methyl-benzoato-κO)manganese(II)]-μ-aqua-bis-(μ-4-methyl-benzoato-κO:O')[(4-methyl-benzoato-κO)manganese(II)]-bis-(μ-N,N-diethyl-nicotinamide)-κN:O;O:N].

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catena-Poly[[[bis-(4-methyl-benzoato-?O,O')zinc(II)]-?-4,4'-bipyridine-?N:N'] tetra-hydrate].

Project description:The asymmetric unit of the title compound, {[Zn(C(7)H(7)O(2))(2)(C(10)H(8)N(2))]·4H(2)O}(n), contains a highly distorted octa-hedral Zn(II) metal center strongly coordinated by two N atoms of two 4,4'-bipyridine (4,4'-bipy) ligands and chelated by two 4-methyl-benzoate anions. The crystallographic inversion center and glide plane present at the center of the C-C single bond of 4,4'-bipy, along with the cis coordination motif of the 4,4'-bipy, lead to one-dimensional zigzag chains. There are a large number of water mol-ecules in the crystal structure, which also form one-dimensional chains through O-H?O hydrogen bonds.

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catena-Poly[[bis-(5-chloro-2-nitro-benzoato)copper(II)]-bis-(?-5-chloro-2-nitro-benzoato)].

Project description:In the title compound, [Cu(2)(C(7)H(3)ClNO(4))(4)](n), the coordination geometry around each Cu(II) ion is distorted square-pyramidal. The CuO(5) coordination is formed by five O atoms from the carboxyl-ate groups of five 5-chloro-2-nitro-benzoate ligands. This coordination leads to the formation of centrosymmetric binuclear units which are edge-shared, forming a linear chain along the a axis, with the Cu(II) ions alternately separated by 2.5891?(4) and 3.1763?(4)?Å. The chains are inter-connected into a three-dimensional network by C-H?O inter-actions.

| S-EPMC2968352 | biostudies-literature

catena-Poly[[[diaqua-cadmium(II)]-bis-[μ-3,5-bis-(isonicotinamido)benzoato]] tetra-hydrate].

Project description:The title compound, {[Cd(C(19)H(13)N(4)O(4))(2)(H(2)O)(2)]·4H(2)O}(n) or {[Cd(BBA)(2)(H(2)O)(2)]·4H(2)O}(n), where BBA is 3,5-bis-(iso-nicotin-amido)-benzoate, is isotypic with its Mn isologue [Chen et al. (2009 ▶). J. Coord. Chem.62, 2421-2428]. The cation sits on a twofold axis and is six-coordinated in a slightly distorted octa-hedral geometry; the polyhedra are linked into zigzag chains, which are further connected by N-H⋯O, O-H⋯O and O-H⋯N hydrogen bonds as well as π-π inter-actions [centroid-centroid distance of 3.639 (2) Å], giving a three-dimensional supra-molecular framework.

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catena-Poly[[aqua-(3-methyl-benzoato-?O,O')lead(II)]-?-3-methyl-benzoato-?O:O,O':O'].

Project description:The reaction of lead(II) acetate and 3-methyl-benzoic acid (MBA) in aqueous solution yielded the title polymer, [Pb(C(8)H(7)O(2))(2)(H(2)O)](n). The asymmetric unit contains two Pb(II) atoms, four MBA ligands and two water mol-ecules. Each Pb(II) cation is hepta-coordinated and chelated by four carboxyl-ate O atoms from two MBA ligands. The Pb atoms are bridged through the carboxyl-ate O atoms from another two MBA ligands, leading to a central Pb(2)O(2) core. The Pb-O bond lengths are in the range 2.325?(3)-2.757?(4)?Å. The intra- and inter-dimer Pb?Pb distances are 4.2942?(3) and 4.2283?(3)?Å, respectively, indicating little direct metal-metal inter-action. The coordinating water mol-ecules and carboxyl-ate O atoms are involved in extensive O-H?O hydrogen-bonding inter-actions. The complex has an extended ladder-like chain structure and the chains are assembled by hydrogen bonds and ?-? inter-actions [centroid-centroid distance = 3.6246?(3)?Å] into a three-dimensional supra-molecular structure.

| S-EPMC2969469 | biostudies-literature

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