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4-{2-[2-(4-Formyl-phen-oxy)eth-oxy]eth-oxy}benzaldehyde.


ABSTRACT: The title compound, C(18)H(18)O(5), was obtained by the reaction of 4-hy-droxy-benzaldehyde with bis-(2,2-dichloro-eth-yl) ether in dimethyl-formamide. In the crystal, the mol-ecule lies on a twofold rotation axis that passes through the central O atom of the aliphatic chain, thus leading to one half-mol-ecule being present per asymmetric unit. The carbonyl, aryl and O-CH(2)-CH(2) groups are almost coplanar, with an r.m.s. deviation of 0.030?Å. The aromatic rings are approximately perpendicular to each other, forming a dihedral angle of 78.31?sh;H?O hydrogen bonds and C-H?? inter-actions help to consolidate the three-dimensional network.

SUBMITTER: Ma Z 

PROVIDER: S-EPMC3120494 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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4-{2-[2-(4-Formyl-phen-oxy)eth-oxy]eth-oxy}benzaldehyde.

Ma Zhen Z   Cao Yiqun Y  

Acta crystallographica. Section E, Structure reports online 20110525 Pt 6


The title compound, C(18)H(18)O(5), was obtained by the reaction of 4-hy-droxy-benzaldehyde with bis-(2,2-dichloro-eth-yl) ether in dimethyl-formamide. In the crystal, the mol-ecule lies on a twofold rotation axis that passes through the central O atom of the aliphatic chain, thus leading to one half-mol-ecule being present per asymmetric unit. The carbonyl, aryl and O-CH(2)-CH(2) groups are almost coplanar, with an r.m.s. deviation of 0.030 Å. The aromatic rings are approximately perpendicular  ...[more]

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