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Chloridobis(1,10-phenanthroline-?N,N')copper(II) tetra-kis-(nitrato-?O,O')(1,10-phenanthroline-?N,N')terbate(III).

ABSTRACT: The title complex salt, [CuCl(C(12)H(8)N(2))(2)][Tb(NO(3))(4)(C(12)H(8)N(2))], consists of discrete [CuCl(phen))(2)](+) cations and [Tb(NO(3))(4)(phen)](-) anions (phen is 1,10-phenanthroline). The [CuCl(phen))(2)](+) cation contains a five-coordinate Cu(2+) ion, ligated by two bidentate phen ligands and one Cl(-) ion, exhibiting a distorted CuN(4)Cl trigonal-bipyramidal geometry. In the [Tb(NO(3))(4)(phen)](-) anion, the Tb(3+) ion is coordinated by one chelating phen ligand and four chelating nitrates, forming a distorted TbN(2)O(8) bicapped dodeca-hedral configuration. The anions and cations are assembled into a three-dimensional network by weak C-H?Cl and C-H?O hydrogen bonds. There is also a significant ?-? stacking inter-action, with a centroid-centroid distance of 3.635?(2)?Å.

SUBMITTER: Gao GR

PROVIDER: S-EPMC3120589 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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Chloridobis(1,10-phenanthroline-κN,N')copper(II) tetra-kis-(nitrato-κO,O')(1,10-phenanthroline-κN,N')terbate(III).

Gao Guo-Ran GR Man Hong-Xue HX Xiao Zhi-Chang ZC Deng Yu-Heng YH

Acta crystallographica. Section E, Structure reports online 20110525 Pt 6

The title complex salt, [CuCl(C(12)H(8)N(2))(2)][Tb(NO(3))(4)(C(12)H(8)N(2))], consists of discrete [CuCl(phen))(2)](+) cations and [Tb(NO(3))(4)(phen)](-) anions (phen is 1,10-phenanthroline). The [CuCl(phen))(2)](+) cation contains a five-coordinate Cu(2+) ion, ligated by two bidentate phen ligands and one Cl(-) ion, exhibiting a distorted CuN(4)Cl trigonal-bipyramidal geometry. In the [Tb(NO(3))(4)(phen)](-) anion, the Tb(3+) ion is coordinated by one chelating phen ligand and four chelating ...[more]

PMID: 21754668

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