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Catena-Poly[[dichloridozinc(II)]-?-1,4-bis-(pyridin-2-ylmeth-oxy)benzene-?N:N'].

ABSTRACT: In the title compound, [ZnCl(2)(C(18)H(16)N(2)O(2))](n), the Zn(II) ion is tetra-hedrally coordinated by two Cl atoms and by two N atoms from different 1,4-bis-(pyridin-2-ylmeth-oxy)benzene ligands. The ligand shows a non-planar configuration, in which the dihedral angles between the two terminal pyridine rings and the linking benzene ring are 7.86?(12) and 70.74?(11)°. The flexible ligand coordinates to the Zn(II) ions, generating an infinite chain propagating along [001].

SUBMITTER: Liu Y

PROVIDER: S-EPMC3201249 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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catena-Poly[[dichloridozinc(II)]-μ-1,4-bis-(pyridin-2-ylmeth-oxy)benzene-κN:N'].

Liu Ying Y Zhang Hong-Sen HS Hu Ming-Xing MX Hou Guang-Feng GF Gao Jin-Sheng JS

Acta crystallographica. Section E, Structure reports online 20110914 Pt 10

In the title compound, [ZnCl(2)(C(18)H(16)N(2)O(2))](n), the Zn(II) ion is tetra-hedrally coordinated by two Cl atoms and by two N atoms from different 1,4-bis-(pyridin-2-ylmeth-oxy)benzene ligands. The ligand shows a non-planar configuration, in which the dihedral angles between the two terminal pyridine rings and the linking benzene ring are 7.86 (12) and 70.74 (11)°. The flexible ligand coordinates to the Zn(II) ions, generating an infinite chain propagating along [001]. ...[more]

PMID: 22058696

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