Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

1,5-Bis(4-meth-oxy-benzyl-idene)thio-carbonohydrazide methanol monosolvate.

ABSTRACT: In the title compound, C(17)H(18)N(4)O(2)S·CH(3)OH, the two benzene rings in the thio-carbonohydrazide mol-ecule form a dihedral angle of 22.42?(18)°. Pairs of N-H?S hydrogen bonds link thio-carbonohydrazide mol-ecules into centrosymmetric dimers. Methanol solvent mol-ecules serve as donors (O-H?S and O-H?N) and acceptors (N-H?O and C-H?O) of weak inter-molecular hydrogen bonds, which link further these dimers into double ribbons along the b axis.

SUBMITTER: Zhao X

PROVIDER: S-EPMC3213573 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

1,5-Bis(4-meth-oxy-benzyl-idene)thio-carbonohydrazide methanol monosolvate.

Zhao Xinyu X

Acta crystallographica. Section E, Structure reports online 20110723 Pt 8

In the title compound, C(17)H(18)N(4)O(2)S·CH(3)OH, the two benzene rings in the thio-carbonohydrazide mol-ecule form a dihedral angle of 22.42 (18)°. Pairs of N-H⋯S hydrogen bonds link thio-carbonohydrazide mol-ecules into centrosymmetric dimers. Methanol solvent mol-ecules serve as donors (O-H⋯S and O-H⋯N) and acceptors (N-H⋯O and C-H⋯O) of weak inter-molecular hydrogen bonds, which link further these dimers into double ribbons along the b axis. ...[more]

PMID: 22091150

Similar Datasets

1,5-Bis(2-meth-oxy-benzyl-idene)thio-carbonohydrazide methanol monosolvate.

Project description:The title compound, C17H18N4O2S·CH3OH, was synthesized by the condensation reaction of o-meth-oxy-benzaldehyde with thio-carbohydrazide in methanol. The two benzene rings are inclined each to other at 31.7 (1)°. Inter-molecular N-H⋯O and bifurcated O-H⋯N(S) hydrogen bonds link two thio-carbonohydrazide and two solvent mol-ecules into a centrosymmetric unit. These units, related by translation along the b axis, are further aggregated into columns through N-H⋯S hydrogen bonds.

| S-EPMC3770410 | biostudies-literature

1,5-Bis(2-hy-droxy-3-meth-oxy-benzyl-idene)carbonohydrazide methanol 0.47-solvate.

Project description:In the title compound, C17H18N4O5·0.47CH3OH, the virtually planar (r.m.s. deviation = 0.128 Å) carbonohydrazide mol-ecule is located on a twofold axis and conformation of its C=N bonds is E. There are short intra-molecular O-H⋯N hydrogen bonds between the hy-droxy groups and hydrazide N atoms. In the crystal, bifurcated N-H⋯(O,O) hydrogen bonds assemble the carbonohydrazide mol-ecules into a three-dimensional network. There are C 2 symmetric voids in this network, 47% of which are occupied by disordered methanol mol-ecules.

| S-EPMC3998575 | biostudies-literature

1,5-Bis[1-(4-meth-oxy-phen-yl)ethyl-idene]thio-carbonohydrazide.

Project description:In the title mol-ecule, C(19)H(22)N(4)O(2)S, the two benzene rings form a dihedral angle of 9.16?(13)°. In the crystal, pairs of weak inter-molecular C-H?S hydrogen bonds link the mol-ecules into centrosymmetric dimers, which are further linked through weak C-H?O inter-actions into sheets parallel to (012).

| S-EPMC3213572 | biostudies-literature

1,5-Bis(4-iso-propyl-benzyl-idene)thio-carbonohydrazide.

Project description:The title compound, C21H26N4S, was synthesized by the condensation reaction of 4-iso-propyl-benzaldehyde with thio-carbohydrazide in ethanol. The planes of the two benzene rings in the mol-ecule are inclined at 22.6?(1)°. In the crystal, pairs of inter-molecular N-H?S hydrogen bonds link the mol-ecules into inversion dimers.

| S-EPMC3884323 | biostudies-literature

1,5-Bis(2-oxoindolin-3-yl-idene)thio-carbonohydrazide tetra-hydro-furan monosolvate.

Project description:In the thio-carbonohydrazide mol-ecule of the title compound, C(17)H(12)N(6)O(2)S·C(4)H(8)O, the terminal indolin-2-one ring systems make a dihedral angle of 20.13?(6)° with each other. Two intra-molecular N-H?O hydrogen bonds are present, each of which generates an S(6) ring. In the crystal, N-H?O hydrogen bonds lead to a mol-ecular chain running along the b axis. The tetra-hydro-furan solvent mol-ecule is disordered over two orientations in a 0.561?(11):0.439?(11) ratio.

| S-EPMC3379434 | biostudies-literature

1,5-Bis(2-chloro-benzyl-idene)carbonohydrazide.

Project description:In the title mol-ecule, C(15)H(12)Cl(2)N(4)O, the two benzene rings are inclined at a dihedral angle of 14.5?(2)°. In the crystal, inter-molecular N-H?O hydrogen bonds link mol-ecules into chains propagated in [001].

| S-EPMC2977268 | biostudies-literature

4-Chloro-N'-(4-meth-oxy-benzyl-idene)benzohydrazide methanol monosolvate.

Project description:The title compound, C(15)H(13)ClN(2)O(2)·CH(4)O, consists of a 4-chloro-N'-(4-meth-oxy-benzyl-idene)benzohydrazide (CMB) mol-ecule and a methanol mol-ecule of crystallization. It was obtained by the condensation of 4-meth-oxy-benzaldehyde with 4-chloro-benzohydrazide. In the CMB mol-ecule, the dihedral angle between the two benzene rings is 50.1?(3)°. The methanol mol-ecule is linked to the CMB mol-ecule through O-H?O and O-H?N hydrogen bonds. In the crystal, CMB mol-ecules are linked through inter-molecular N-H?O hydrogen bonds, involving the methanol mol-ecule, forming chains propagating along [010].

| S-EPMC3009357 | biostudies-literature

(E)-4-Meth-oxy-N'-(4-nitro-benzyl-idene)benzohydrazide methanol monosolvate.

Project description:The hydrazone mol-ecule of the title compound, C(15)H(13)N(3)O(4)·CH(4)O, is nearly planar, with a dihedral angle between the two benzene rings of 1.2?(4)°. The mol-ecule exists in a trans configuration with respect to the central methyl-idene unit. In the crystal, the benzohydrazide and methanol mol-ecules are linked through inter-molecular O-H?O, O-H?N and N-H?O hydrogen bonds, forming chains along the a axis.

| S-EPMC3011623 | biostudies-literature

1,5-Bis[1-(4-bromo-phen-yl)ethyl-idene]thio-carbonohydrazide.

Project description:The asymmetric unit of the title compound, C17H16Br2N4S, contains two independent mol-ecules in which the benzene rings form dihedral angles of 20.0?(1) and 55.3?(1)°. In the crystal, a pair of N-H?S hydrogen bonds link the two different independent mol-ecules into a dimer.

| S-EPMC3648255 | biostudies-literature

N'-(3-Fluoro-benzyl-idene)-4-hy-droxy-3-meth-oxy-benzohydrazide methanol monosolvate.

Project description:In the title compound, C(15)H(13)FN(2)O(3)·CH(3)OH, the dihedral angle between the benzene rings of the benzohydrazone mol-ecule is 5.3 (3)°. The C atom of the meth-oxy group is almost coplanar with its attached ring [deviation = 0.017 (2) Å]. The r.m.s. deviation of the 21 non-H atoms of the hydrazone mol-ecule is 0.106 Å. In the crystal, the components are linked by O(m)-H⋯O(h), N(h)-H⋯O(m) and O(h)-H⋯O(h) (m = methanol and h = hydrazone) hydrogen bonds, forming (001) layers.

| S-EPMC3344474 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data