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Copper-catalyzed arylation of 1H-perfluoroalkanes.


ABSTRACT: A general method has been developed for arylation of readily available 1H-perfluoroalkanes. The method employs aryl iodide and 1H-perfluoroalkane reagents, DMPU solvent, TMP(2)Zn base, and a copper chloride/phenanthroline catalyst. Preliminary mechanistic studies are reported.

SUBMITTER: Popov I 

PROVIDER: S-EPMC3122272 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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Copper-catalyzed arylation of 1H-perfluoroalkanes.

Popov Ilya I   Lindeman Sergey S   Daugulis Olafs O  

Journal of the American Chemical Society 20110531 24


A general method has been developed for arylation of readily available 1H-perfluoroalkanes. The method employs aryl iodide and 1H-perfluoroalkane reagents, DMPU solvent, TMP(2)Zn base, and a copper chloride/phenanthroline catalyst. Preliminary mechanistic studies are reported. ...[more]

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