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Total synthesis of bryostatin 9.


ABSTRACT: The total synthesis of bryostatin 9 was accomplished using a uniquely step-economical and convergent Prins-driven macrocyclization strategy. At 25 linear and 42 total steps, this is currently the most concise and convergent synthesis of a potent bryostatin.

SUBMITTER: Wender PA 

PROVIDER: S-EPMC3129979 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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Total synthesis of bryostatin 9.

Wender Paul A PA   Schrier Adam J AJ  

Journal of the American Chemical Society 20110527 24


The total synthesis of bryostatin 9 was accomplished using a uniquely step-economical and convergent Prins-driven macrocyclization strategy. At 25 linear and 42 total steps, this is currently the most concise and convergent synthesis of a potent bryostatin. ...[more]

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