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2-Diazo-1-(1,1-dioxothio-morpholin-4-yl)ethanone.

ABSTRACT: In the mol-ecule of the title compound, C(6)H(9)N(3)O(3)S, at 105?K, the six-membered ring is predominantly found in the chair conformation, with 1.89?(14)% in the boat conformation. In the crystal structure, there are five inter-molecular C-H?O=C and C-H?O=S contacts less than 2.6?Å, as well as a weak C-H?N=N inter-action to the diazo group.

SUBMITTER: Kaupang A

PROVIDER: S-EPMC3151793 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

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2-Diazo-1-(1,1-dioxothio-morpholin-4-yl)ethanone.

Kaupang Asmund A Görbitz Carl Henrik CH Hansen Tore T

Acta crystallographica. Section E, Structure reports online 20110630 Pt 7

In the mol-ecule of the title compound, C(6)H(9)N(3)O(3)S, at 105 K, the six-membered ring is predominantly found in the chair conformation, with 1.89 (14)% in the boat conformation. In the crystal structure, there are five inter-molecular C-H⋯O=C and C-H⋯O=S contacts less than 2.6 Å, as well as a weak C-H⋯N=N inter-action to the diazo group. ...[more]

PMID: 21837210

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