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Catena-Poly[[[tetra-aqua-cobalt(II)]-μ-4,4'-bipyridine-κN:N'] pyridine-3,5-dicarboxyl-ate trihydrate].

ABSTRACT: The crystal structure of the title compound, {[Co(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(3)NO(4))·3H(2)O}(n), consists of Co(II) polymeric complex cations, uncoordinated pyridine-3,5-dicarboxyl-ate anions and lattice water mol-ecules. The Co(II) cation is coordinated by two N atoms from two 4,4'-bipyridine ligands and four water mol-ecules in a distorted octa-hedral geometry. The 4,4'-bipyridine ligands bridge Co cations, forming a polymeric chain running along the b axis. The two pyridine rings of the 4,4'-biyridine are twisted to each other by a dihedral angle of 8.95 (9)°. Extensive O-H⋯O hydrogen bonding network is present in the crystal structure.

SUBMITTER: Zhu XD 

PROVIDER: S-EPMC3151975 | biostudies-literature |

REPOSITORIES: biostudies-literature

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