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A new Mo Schiff base complex: methanol[N'-(3-meth-oxy-2-oxidobenzyl-idene)benzohydrazidato]dioxido-molybdenum(VI).

ABSTRACT: In the title benzil-idene Schiff base molybdenum(VI) complex, [Mo(C(15)H(12)N(2)O(3))O(2)(CH(3)OH)], the Mo(VI) ion is coordinated by two oxide O atoms and by two O atoms and one N atom of the tridentate N'-(3-meth-oxy-2-oxidobenzyl-idene)benzo-hydrazidate (L) Schiff base ligand. The methanol O atom completes the distorted octa-hedral configuration of the Mo(VI) atom. Strong O-H?N hydrogen bonds form a C(5) chain around a 2(1) screw axis. Weak C-H-O hydrogen bonds are also present.

SUBMITTER: Sheikhshoaie I

PROVIDER: S-EPMC3152014 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

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A new Mo Schiff base complex: methanol[N'-(3-meth-oxy-2-oxidobenzyl-idene)benzohydrazidato]dioxido-molybdenum(VI).

Sheikhshoaie Iran I Langer Vratislav V Yasrebi Seyed Ali SA

Acta crystallographica. Section E, Structure reports online 20110604 Pt 7

In the title benzil-idene Schiff base molybdenum(VI) complex, [Mo(C(15)H(12)N(2)O(3))O(2)(CH(3)OH)], the Mo(VI) ion is coordinated by two oxide O atoms and by two O atoms and one N atom of the tridentate N'-(3-meth-oxy-2-oxidobenzyl-idene)benzo-hydrazidate (L) Schiff base ligand. The methanol O atom completes the distorted octa-hedral configuration of the Mo(VI) atom. Strong O-H⋯N hydrogen bonds form a C(5) chain around a 2(1) screw axis. Weak C-H-O hydrogen bonds are also present. ...[more]

PMID: 21836845

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