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Catena-Poly[[[aqua-(di-2-pyridyl-amine-?N,N)manganese(II)]-?-5-ferrocenyl-benzene-1,3-dicarboxyl-ato-?O,O:O] methanol monosolvate monohydrate].

ABSTRACT: In the title coordination polymer, {[FeMn(C(5)H(5))(C(13)H(7)O(4))(C(10)H(9)N(3))(H(2)O)]·CH(3)OH·H(2)O}(n), the Mn(II) ion has a distorted octa-hedral coordination geometry and is ligated by two N atoms from two di-2-pyridyl-amine mol-ecules, three O atoms from two 5-ferrocenyl-benzene-1,3-dicarboxyl-ate anions and one O atom from a coordinated water mol-ecule. The Mn-O distances range from 2.151?(2) to 2.5093?(19)?Å, while the Mn-N distances are 2.226?(2) and 2.248?(2)?Å. Each 5-ferrocenyl-benzene-1,5-dicarboxyl-ate anion links to two Mn(II) ions, resulting in a chain along the b axis. A three-dimensional network of N-H?O and O-H?O hydrogen bonds helps to stabilize the crystal packing.

SUBMITTER: Liu W

PROVIDER: S-EPMC3152059 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

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catena-Poly[[[aqua-(di-2-pyridyl-amine-κN,N)manganese(II)]-μ-5-ferrocenyl-benzene-1,3-dicarboxyl-ato-κO,O:O] methanol monosolvate monohydrate].

Liu Wei W Zhang Gang G

Acta crystallographica. Section E, Structure reports online 20110625 Pt 7

In the title coordination polymer, {[FeMn(C(5)H(5))(C(13)H(7)O(4))(C(10)H(9)N(3))(H(2)O)]·CH(3)OH·H(2)O}(n), the Mn(II) ion has a distorted octa-hedral coordination geometry and is ligated by two N atoms from two di-2-pyridyl-amine mol-ecules, three O atoms from two 5-ferrocenyl-benzene-1,3-dicarboxyl-ate anions and one O atom from a coordinated water mol-ecule. The Mn-O distances range from 2.151 (2) to 2.5093 (19) Å, while the Mn-N distances are 2.226 (2) and 2.248 (2) Å. Each 5-ferrocenyl-ben ...[more]

PMID: 21836962

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