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Cross-couplings between benzylic and aryl halides "on water": synthesis of diarylmethanes.


ABSTRACT: A remarkably simple entry to unsymmetrical diarylmethanes has been developed that relies on an in situ organozinc-mediated, palladium-catalyzed cross-coupling. Thus, by mixing a benzyl and aryl halide together in the presence of Zn metal and a Pd catalyst, diarylmethanes are formed at room temperature without assistance by a surfactant; hence, "on water".

SUBMITTER: Duplais C 

PROVIDER: S-EPMC3152455 | biostudies-literature | 2010 Jan

REPOSITORIES: biostudies-literature

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Cross-couplings between benzylic and aryl halides "on water": synthesis of diarylmethanes.

Duplais Christophe C   Krasovskiy Arkady A   Wattenberg Alina A   Lipshutz Bruce H BH  

Chemical communications (Cambridge, England) 20091209 4


A remarkably simple entry to unsymmetrical diarylmethanes has been developed that relies on an in situ organozinc-mediated, palladium-catalyzed cross-coupling. Thus, by mixing a benzyl and aryl halide together in the presence of Zn metal and a Pd catalyst, diarylmethanes are formed at room temperature without assistance by a surfactant; hence, "on water". ...[more]

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