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Stereoselective Negishi-like couplings between alkenyl and alkyl halides in water at room temperature.

ABSTRACT: Mix in water and then stir. That is all that is required in this new approach to stereoselective sp(3)-sp(2) cross-couplings between an alkyl and alkenyl halide. Prior formation of organozinc reagents is not required.

SUBMITTER: Krasovskiy A

PROVIDER: S-EPMC3365513 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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Stereoselective Negishi-like couplings between alkenyl and alkyl halides in water at room temperature.

Krasovskiy Arkady A Duplais Christophe C Lipshutz Bruce H BH

Organic letters 20101101 21

Mix in water and then stir. That is all that is required in this new approach to stereoselective sp(3)-sp(2) cross-couplings between an alkyl and alkenyl halide. Prior formation of organozinc reagents is not required. ...[more]

PMID: 20882969

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