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Expedient synthesis of N-acyl anthranilamides and ?-enamine amides by the Rh(III)-catalyzed amidation of aryl and vinyl C-H bonds with isocyanates.


ABSTRACT: A Rh(III)-catalyzed protocol for the amidation of anilide and enamide C-H bonds with isocyanates has been developed. This method provides direct and efficient syntheses of N-acyl anthranilamides, enamine amides, and pyrimidin-4-one heterocycles.

SUBMITTER: Hesp KD 

PROVIDER: S-EPMC3158987 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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Expedient synthesis of N-acyl anthranilamides and β-enamine amides by the Rh(III)-catalyzed amidation of aryl and vinyl C-H bonds with isocyanates.

Hesp Kevin D KD   Bergman Robert G RG   Ellman Jonathan A JA  

Journal of the American Chemical Society 20110708 30


A Rh(III)-catalyzed protocol for the amidation of anilide and enamide C-H bonds with isocyanates has been developed. This method provides direct and efficient syntheses of N-acyl anthranilamides, enamine amides, and pyrimidin-4-one heterocycles. ...[more]

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