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Chlorido(8-hy-droxy-quinoline-?N,O)(quinolin-8-olato-?N,O)zinc methanol monosolvate.

ABSTRACT: In the title compound, [Zn(C(9)H(6)NO)Cl(C(9)H(7)NO)]·CH(3)OH, the Zn(II) ion is N,O-chelated by both a neutral and a deprotonated quinolin-8-ol ligand, with a chloride ligand in the apical site completing the square-pyramidal coordination geometry. The Zn(II) ion is displaced by 0.586?Å in the direction of the chloride ligand from the atoms forming the square plane. In the crystal, the components are linked by inter-molecular O-H?O hydrogen bonds, generating chains along the b axis.

SUBMITTER: Najafi E

PROVIDER: S-EPMC3200687 | biostudies-literature | 2011 Sep

REPOSITORIES: biostudies-literature

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Chlorido(8-hy-droxy-quinoline-κN,O)(quinolin-8-olato-κN,O)zinc methanol monosolvate.

Najafi Ezzatollah E Amini Mostafa M MM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20110827 Pt 9

In the title compound, [Zn(C(9)H(6)NO)Cl(C(9)H(7)NO)]·CH(3)OH, the Zn(II) ion is N,O-chelated by both a neutral and a deprotonated quinolin-8-ol ligand, with a chloride ligand in the apical site completing the square-pyramidal coordination geometry. The Zn(II) ion is displaced by 0.586 Å in the direction of the chloride ligand from the atoms forming the square plane. In the crystal, the components are linked by inter-molecular O-H⋯O hydrogen bonds, generating chains along the b axis. ...[more]

PMID: 22058878

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