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8-Hy-droxy-2-methyl-quinolinium tetra-chlorido(quinolin-2-olato-?N,O)stannate(IV) methanol disolvate.

ABSTRACT: In the reaction of 8-hy-droxy-quinoline, 2-methyl-8-hy-droxy-quinoline and stannic chloride, the 2-methyl-8-hy-droxy-quinoline is protonated, yielding the disolvated title salt, (C(10)H(10)NO)[SnCl(4)(C(9)H(6)NO)]·2CH(3)OH. The Sn(IV) atom in the anion is N,O-chelated by the hy-droxy-quinolinate in a cis-SnNOCl(4) octa-hedral geometry. In the crystal, the cation, anion and solvent mol-ecules are linked by N-H?O, O-H?O and O-H?Cl hydrogen bonds, generating a three-dimensional network.

SUBMITTER: Najafi E

PROVIDER: S-EPMC3051736 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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8-Hy-droxy-2-methyl-quinolinium tetra-chlorido(quinolin-2-olato-κN,O)stannate(IV) methanol disolvate.

Najafi Ezzatollah E Amini Mostafa M MM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20110122 Pt 2

In the reaction of 8-hy-droxy-quinoline, 2-methyl-8-hy-droxy-quinoline and stannic chloride, the 2-methyl-8-hy-droxy-quinoline is protonated, yielding the disolvated title salt, (C(10)H(10)NO)[SnCl(4)(C(9)H(6)NO)]·2CH(3)OH. The Sn(IV) atom in the anion is N,O-chelated by the hy-droxy-quinolinate in a cis-SnNOCl(4) octa-hedral geometry. In the crystal, the cation, anion and solvent mol-ecules are linked by N-H⋯O, O-H⋯O and O-H⋯Cl hydrogen bonds, generating a three-dimensional network. ...[more]

PMID: 21522896

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