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Bromido(quinolin-8-ol-?N,O)(quinolin-8-olato-?N,O)zinc(II) methanol monosolvate.

ABSTRACT: The title compound, [ZnBr(C(9)H(6)NO)(C(9)H(7)NO)]·CH(3)OH, has its metal atom N,O-chelated by a neutral and a deproton-ated 8-hy-droxy-quinoline ligand. The hy-droxy unit of the neutral ligand is a hydrogen-bond donor to the methanol O atom and the alk-oxy O atom of the monoanionic ligand is a hydrogen-bond acceptor to the methanol O atom. In the crystal, adjacent mol-ecules are linked by these two hydrogen bonds, generating a chain running along the a axis.

SUBMITTER: Najafi E

PROVIDER: S-EPMC2983236 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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Bromido(quinolin-8-ol-κN,O)(quinolin-8-olato-κN,O)zinc(II) methanol monosolvate.

Najafi Ezzatollah E Amini Mostafa M MM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20100918 Pt 10

The title compound, [ZnBr(C(9)H(6)NO)(C(9)H(7)NO)]·CH(3)OH, has its metal atom N,O-chelated by a neutral and a deproton-ated 8-hy-droxy-quinoline ligand. The hy-droxy unit of the neutral ligand is a hydrogen-bond donor to the methanol O atom and the alk-oxy O atom of the monoanionic ligand is a hydrogen-bond acceptor to the methanol O atom. In the crystal, adjacent mol-ecules are linked by these two hydrogen bonds, generating a chain running along the a axis. ...[more]

PMID: 21587422

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