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Dichloridotetra-kis-(diniconazole)cobalt(II).

ABSTRACT: In the crystal structure of the title compound, [CoCl(2)(C(15)H(17)Cl(2)N(3)O)(4)], the Co(II) cation lies on an inversion center and has a slightly distorted octa-hedral coordination geometry. The equatorial positions are occupied by four N atoms from four diniconazole [systematic name: (E)-(RS)-1-(2,4-dichloro-phen-yl)-4,4-dimethyl-2-(1H-1,2,4-triazol-1-yl)pent-1-en-3-ol] ligands. The axial sites are occupied by two Cl(-) anions. In the two independent organic ligands, the triazole ring is oriented at dihedral angles of 18.28?(14) and 32.15?(14)° with respect to the dichloro-phenyl ring. Inter-molecular O-H?Cl hydrogen bonds consolidate the crystal packing.

SUBMITTER: Liu CX

PROVIDER: S-EPMC3200721 | biostudies-literature | 2011 Sep

REPOSITORIES: biostudies-literature

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Dichloridotetra-kis-(diniconazole)cobalt(II).

Liu Chang-Xiang CX Song Xiu-Ying XY Liu Qian Q Nie Xu-Liang XL Wen Shi-He SH

Acta crystallographica. Section E, Structure reports online 20110811 Pt 9

In the crystal structure of the title compound, [CoCl(2)(C(15)H(17)Cl(2)N(3)O)(4)], the Co(II) cation lies on an inversion center and has a slightly distorted octa-hedral coordination geometry. The equatorial positions are occupied by four N atoms from four diniconazole [systematic name: (E)-(RS)-1-(2,4-dichloro-phen-yl)-4,4-dimethyl-2-(1H-1,2,4-triazol-1-yl)pent-1-en-3-ol] ligands. The axial sites are occupied by two Cl(-) anions. In the two independent organic ligands, the triazole ring is ori ...[more]

PMID: 22065723

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