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Cis-Dichloridobis{[4-(dimethyl-amino)-phen-yl]diphenyl-phosphane-?P}platinum(II) ethyl acetate monosolvate.

ABSTRACT: The title compound, [PtCl(2)(C(20)H(20)P)(2)]·C(4)H(8)O(2), crystallizes with the Pt atom in a distorted cis-square-planar geometry. The Pt-P bond lengths are 2.2490?(19) and 2.253?(2)?Å, and the Pt-Cl bond lengths are 2.344?(2) and 2.3475?(18)?Å. Some weak C-H?Cl and C-H?O inter-actions involving the solvate mol-ecule were observed.

SUBMITTER: Muller A

PROVIDER: S-EPMC3201384 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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cis-Dichloridobis{[4-(dimethyl-amino)-phen-yl]diphenyl-phosphane-κP}platinum(II) ethyl acetate monosolvate.

Muller Alfred A Meijboom Reinout R

Acta crystallographica. Section E, Structure reports online 20110914 Pt 10

The title compound, [PtCl(2)(C(20)H(20)P)(2)]·C(4)H(8)O(2), crystallizes with the Pt atom in a distorted cis-square-planar geometry. The Pt-P bond lengths are 2.2490 (19) and 2.253 (2) Å, and the Pt-Cl bond lengths are 2.344 (2) and 2.3475 (18) Å. Some weak C-H⋯Cl and C-H⋯O inter-actions involving the solvate mol-ecule were observed. ...[more]

PMID: 22058690

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