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Cis-Dichloridobis[tris-(2-methyl-phen-oxy)phosphane-?P]palladium(II).

ABSTRACT: In the title compound, [PdCl(2)(C(21)H(21)O(3)P)(2)], the Pd atom adopts a slightly distorted square-planar coordination geometry, with pairs of the equivalent ligands in cis positions. Adjacent mol-ecules are linked by weak C-H?Cl hydrogen bonds. The crystal structure is additionally stabilized by ?-? stacking inter-actions between the aromatic rings [shortest centroid-centroid distance = 3.758?(4)?Å].

SUBMITTER: Blaszczyk I

PROVIDER: S-EPMC3297231 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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cis-Dichloridobis[tris-(2-methyl-phen-oxy)phosphane-κP]palladium(II).

Błaszczyk Izabela I Trzeciak Anna M AM Gniewek Andrzej A

Acta crystallographica. Section E, Structure reports online 20120210 Pt 3

In the title compound, [PdCl(2)(C(21)H(21)O(3)P)(2)], the Pd atom adopts a slightly distorted square-planar coordination geometry, with pairs of the equivalent ligands in cis positions. Adjacent mol-ecules are linked by weak C-H⋯Cl hydrogen bonds. The crystal structure is additionally stabilized by π-π stacking inter-actions between the aromatic rings [shortest centroid-centroid distance = 3.758 (4) Å]. ...[more]

PMID: 22412421

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