Unknown

Dataset Information

0

[Bis-(4-methyl-1,3-thia-zol-2-yl-?N)methane]-tricarbonyl-dichlorido-tungsten(II).

ABSTRACT: The title compound, [WCl(2)(C(9)H(10)N(2)S(2))(CO)(3)], is a hepta-coordinate tungsten(II) complex with a capped-octa-hedral coordination sphere in which one CO ligand caps a face formed by a chloro ligand and the two other carbonyls. The chloro ligands are mutually trans positioned at an angle of 156.98?(7)°. The chelating bis-(4-methyl-1,3-thia-zol-2-yl)methane ligand coordinates with the imine N atoms. In the crystal, mol-ecules are linked into chains parallel to [201] by weak C-H?O contacts between the CH(2) group of the bis-(4-methyl-thia-zol-2-yl)methane ligand and the O atom of the capping CO group.

SUBMITTER: Strasser CE 

PROVIDER: S-EPMC3201421 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

[Bis-(4-methyl-1,3-thia-zol-2-yl-κN)methane]-tricarbonyl-dichlorido-tungsten(II).

Strasser Christoph E CE   Cronje Stephanie S   Raubenheimer Helgard G HG  

Acta crystallographica. Section E, Structure reports online 20110930 Pt 10

The title compound, [WCl(2)(C(9)H(10)N(2)S(2))(CO)(3)], is a hepta-coordinate tungsten(II) complex with a capped-octa-hedral coordination sphere in which one CO ligand caps a face formed by a chloro ligand and the two other carbonyls. The chloro ligands are mutually trans positioned at an angle of 156.98 (7)°. The chelating bis-(4-methyl-1,3-thia-zol-2-yl)methane ligand coordinates with the imine N atoms. In the crystal, mol-ecules are linked into chains parallel to [201] by weak C-H⋯O contacts  ...[more]

Similar Datasets

Unknown N,N'-Bis(1,3-thia-zol-2-yl)methyl-ene-diamine.
| S-EPMC3238970 | biostudies-literature
Unknown Bis{?-[4-(1,3-benzothia-zol-2-yl)phen-yl]methane-thiol-ato-?S,S':S,S'}bis-[tricarbonyl-iron(I)](Fe-Fe).
| S-EPMC3297275 | biostudies-literature
Unknown Crystal structure of 3-methyl-2,6-bis-(4-methyl-1,3-thia-zol-5-yl)piperidin-4-one.
| S-EPMC4186075 | biostudies-literature
Unknown 2-(2-Methyl-phen-yl)-N-(1,3-thia-zol-2-yl)acetamide.
| S-EPMC4051114 | biostudies-literature
Unknown 5-Methyl-N-(1,3-thia-zol-2-yl)isoxazole-4-carboxamide.
| S-EPMC3684936 | biostudies-literature
Unknown Bis[(1-methyl-1H-tetra-zol-5-yl)sulfan-yl]methane.
| S-EPMC3100044 | biostudies-literature
Unknown Polymorphism of bis-(1,3-benzo-thia-zol-2-yl) tri-thio-carbonate.
| S-EPMC7336794 | biostudies-literature
Unknown (E)-Methyl 1,3-thia-zol-2-yl ketone 2,4-dinitro-phenyl-hydrazone.
| S-EPMC2961542 | biostudies-literature
Unknown 2,9-Bis(1,3-benzothia-zol-2-yl)-1,10-phenanthroline dichloro-methane disolvate.
| S-EPMC2960670 | biostudies-literature
Unknown N-(1,3-Thia-zol-2-yl)benzamide.
| S-EPMC2969069 | biostudies-literature