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Crystal structure of 3-methyl-2,6-bis-(4-methyl-1,3-thia-zol-5-yl)piperidin-4-one.

ABSTRACT: In the title compound, C14H17N3OS2, the central piperidinone ring adopts a chair conformation and the thia-zole rings are inclined to its mean plane by 80.16?(12) and 67.15?(12)°. The O atom and methyl group C atom deviate significantly from the mean plane of the central piperidinone ring, by 0.8138?(2) and 0.3175?(2)?Å, respectively. The dihedral angle between the thia-zole rings is 51.88?(13)°. In the crystal, mol-ecules are linked via C-H?O hydrogen bonds, forming zigzag C(10) chains running parallel to [001].

SUBMITTER: Manimaran A

PROVIDER: S-EPMC4186075 | biostudies-literature | 2014 Sep

REPOSITORIES: biostudies-literature

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Crystal structure of 3-methyl-2,6-bis-(4-methyl-1,3-thia-zol-5-yl)piperidin-4-one.

Manimaran A A Sethusankar K K Ganesan S S Ananthan S S

Acta crystallographica. Section E, Structure reports online 20140830 Pt 9

In the title compound, C14H17N3OS2, the central piperidinone ring adopts a chair conformation and the thia-zole rings are inclined to its mean plane by 80.16 (12) and 67.15 (12)°. The O atom and methyl group C atom deviate significantly from the mean plane of the central piperidinone ring, by 0.8138 (2) and 0.3175 (2) Å, respectively. The dihedral angle between the thia-zole rings is 51.88 (13)°. In the crystal, mol-ecules are linked via C-H⋯O hydrogen bonds, forming zigzag C(10) chains running ...[more]

PMID: 25309222

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