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Poly[[bis-(nitrato-?O)bis-(?(4)-pyridine-4-carboxyl-ato)tetra-kis-(?(3)-pyridine-4-carboxyl-ato)octa-silver(I)] hemihydrate].

ABSTRACT: In the title coordination polymer, {[Ag(8)(C(6)H(4)NO(2))(6)(NO(3))(2)]·0.5H(2)O}(n), two Ag(I) ions are two-coordinate within an AgN(2) set and six are three-coordinate within AgN(2)O and AgO(3) sets. The Ag-N and Ag-O distances are in the ranges 2.150?(5)-2.198?(5) and 2.142?(4)-2.702?(5)?Å, respectively. A two-dimensional coordination network is formed parallel to (100). The O atom of the disordered solvent water mol-ecule is located on an inversion center.

SUBMITTER: Meng ZH

PROVIDER: S-EPMC3212179 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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Poly[[bis-(nitrato-κO)bis-(μ(4)-pyridine-4-carboxyl-ato)tetra-kis-(μ(3)-pyridine-4-carboxyl-ato)octa-silver(I)] hemihydrate].

Meng Zhao-Hui ZH

Acta crystallographica. Section E, Structure reports online 20110723 Pt 8

In the title coordination polymer, {[Ag(8)(C(6)H(4)NO(2))(6)(NO(3))(2)]·0.5H(2)O}(n), two Ag(I) ions are two-coordinate within an AgN(2) set and six are three-coordinate within AgN(2)O and AgO(3) sets. The Ag-N and Ag-O distances are in the ranges 2.150 (5)-2.198 (5) and 2.142 (4)-2.702 (5) Å, respectively. A two-dimensional coordination network is formed parallel to (100). The O atom of the disordered solvent water mol-ecule is located on an inversion center. ...[more]

PMID: 22090881

Similar Datasets

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