Catena-Poly[[(3-methyl-pyridine)-copper(I)]-?-cyanido-copper(I)-?-cyanido].

ABSTRACT: In the title complex, [Cu(2)(CN)(2)(C(6)H(7)N)](n), there are two copper atoms with different coordination environments. One Cu atom (Cu1) is linked to the two cyanide ligands, one N atom from a pyridine ring while the other (Cu2) is coordinated by the two cyanide ligands in a slightly distorted tetra-hedral geometry and linked to Cu1, forming a triangular coordination environment. The Cu atoms are bridged by bidentate cyanide ligands, forming an infinite Cu-CN chain. One cyanide ligand is equally disordered over two sets of sites, exchanging C and N atoms coordinated to both metal atoms. However, one cyanide group is not disordered and it coordinates to Cu1 via the N atom whereas its C-atom counterpart coordinates Cu2. The 3-methyl-pyridine (3MP) ligand coordinates through the N atom to Cu1 as a terminal ligand, which originates from decyanation of 3-pyridyl-acetonitrile under hydro-thermal conditions. Adjacent Cu-CN chains are inter-connected through Cu?Cu inter-actions [2.8364?(10)?Å], forming a three-dimensional framework.

SUBMITTER: Cai JB 

PROVIDER: S-EPMC3212195 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature