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2-(4-Fluoro-phen-yl)-1-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline monohydrate.

ABSTRACT: In the title compound, C(25)H(15)FN(4)·H(2)O, the fused ring system is essentially planar [maximum deviation of 0.0822?(14)?Å]. The imidazole ring makes dihedral angles of 76.83?(7) and 32.22?(7)° with the phenyl group attached to nitro-gen and the fluoro-benzene group to carbon, respectively. The dihedral angle between the two phenyl rings is 72.13?(7)°. Inter-molecular O-H?N, O-H?F, C-H?F, C-H?O and C-H?N hydrogen bonds are found in the crystal structure.

SUBMITTER: Rosepriya S

PROVIDER: S-EPMC3212347 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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2-(4-Fluoro-phen-yl)-1-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline monohydrate.

Rosepriya S S Venkatesh Perumal M M Thiruvalluvar A A Jayabharathi J J Butcher R J RJ Jasinski J P JP Golen J A JA

Acta crystallographica. Section E, Structure reports online 20110709 Pt 8

In the title compound, C(25)H(15)FN(4)·H(2)O, the fused ring system is essentially planar [maximum deviation of 0.0822 (14) Å]. The imidazole ring makes dihedral angles of 76.83 (7) and 32.22 (7)° with the phenyl group attached to nitro-gen and the fluoro-benzene group to carbon, respectively. The dihedral angle between the two phenyl rings is 72.13 (7)°. Inter-molecular O-H⋯N, O-H⋯F, C-H⋯F, C-H⋯O and C-H⋯N hydrogen bonds are found in the crystal structure. ...[more]

PMID: 22091004

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