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5H-Imidazo[4,5-f][1,10]phenanthroline.

ABSTRACT: The title mol-ecule, C(13)H(8)N(4), is is essentially planar [r.m.s. deviation for all non-H atoms = 0.025?(3)?Å]. In the crystal, mol-ecules are connected through one weak bifurcated N-H?(N,N) hydrogen bond and three ?-? stacking inter-actions between pyridine and imidazole rings [centroid-centroid distance = 3.631?(8)?Å] and between pyridine and benzene rings [centroid-centroid distances = 3.675?(5) and 3.666?(2)?Å].

SUBMITTER: Tong SW

PROVIDER: S-EPMC3344565 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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5H-Imidazo[4,5-f][1,10]phenanthroline.

Tong Shao-Wei SW Song Wen-Dong WD Miao Dong-Liang DL An Jing-Bo JB

Acta crystallographica. Section E, Structure reports online 20120421 Pt 5

The title mol-ecule, C(13)H(8)N(4), is is essentially planar [r.m.s. deviation for all non-H atoms = 0.025 (3) Å]. In the crystal, mol-ecules are connected through one weak bifurcated N-H⋯(N,N) hydrogen bond and three π-π stacking inter-actions between pyridine and imidazole rings [centroid-centroid distance = 3.631 (8) Å] and between pyridine and benzene rings [centroid-centroid distances = 3.675 (5) and 3.666 (2) Å]. ...[more]

PMID: 22590327

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