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N'-(5-Bromo-2-hy-droxy-benzyl-idene)-4-nitro-benzohydrazide methanol monosolvate.

ABSTRACT: In the title compound, C(14)H(10)BrN(3)O(4)·CH(4)O, the benzohydrazide mol-ecule is nearly planar [maximum deviation = 0.110?(2)?Å]. The mean planes of the two benzene rings make a dihedral angle of 8.4?(3)°. In the benzohydrazide mol-ecule, there is an intra-molecular O-H?N hydrogen bond and the NH group is hydrogen bonded to the methanol solvent mol-ecule. In the crystal, inter-molecular O-H?O hydrogen bonds involving the methanol solvent mol-ecule link the benzohydrazide mol-ecules to form chains which propagate along the a axis.

SUBMITTER: Liu WH

PROVIDER: S-EPMC3213628 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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N'-(5-Bromo-2-hy-droxy-benzyl-idene)-4-nitro-benzohydrazide methanol monosolvate.

Liu Wei-Hua WH Song Shuang-Ju SJ Ma Jing-Jun JJ

Acta crystallographica. Section E, Structure reports online 20110730 Pt 8

In the title compound, C(14)H(10)BrN(3)O(4)·CH(4)O, the benzohydrazide mol-ecule is nearly planar [maximum deviation = 0.110 (2) Å]. The mean planes of the two benzene rings make a dihedral angle of 8.4 (3)°. In the benzohydrazide mol-ecule, there is an intra-molecular O-H⋯N hydrogen bond and the NH group is hydrogen bonded to the methanol solvent mol-ecule. In the crystal, inter-molecular O-H⋯O hydrogen bonds involving the methanol solvent mol-ecule link the benzohydrazide mol-ecules to form ch ...[more]

PMID: 22091205

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