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{Dimeth-yl [(phenyl-sulfon-yl)amido-]phosphato-?(2) O,O'}bis-(tri-phenylphosphane-?P)copper(I).

ABSTRACT: In the title complex, [Cu(C8H11NO5PS)(C18H15P)2], the Cu(I) ion is coordinated by two tri-phenyl-phosphane mol-ecules and two O atoms of the chelating dimeth-yl(phenyl-sulfon-yl)amido-phosphate anion, generating a squashed CuO2P2 tetrahedron. In the six-membered chelate ring, the Cu, P and O atoms are almost coplanar (r.m.s. deviation = 0.024?Å), with the N and S atoms displaced in the same direction, by 0.708?(5) and 0.429?(2)?Å, respectively.

SUBMITTER: Moroz OV

PROVIDER: S-EPMC4051010 | biostudies-literature | 2014 Jun

REPOSITORIES: biostudies-literature

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{Dimeth-yl [(phenyl-sulfon-yl)amido-]phosphato-κ(2) O,O'}bis-(tri-phenylphosphane-κP)copper(I).

Moroz Olesia V OV Trush Viktor A VA Sliva Tatiana Yu TY Znovjyak Kateryna O KO Amirkhanov Vladimir M VM

Acta crystallographica. Section E, Structure reports online 20140517 Pt 6

In the title complex, [Cu(C8H11NO5PS)(C18H15P)2], the Cu(I) ion is coordinated by two tri-phenyl-phosphane mol-ecules and two O atoms of the chelating dimeth-yl(phenyl-sulfon-yl)amido-phosphate anion, generating a squashed CuO2P2 tetrahedron. In the six-membered chelate ring, the Cu, P and O atoms are almost coplanar (r.m.s. deviation = 0.024 Å), with the N and S atoms displaced in the same direction, by 0.708 (5) and 0.429 (2) Å, respectively. ...[more]

PMID: 24940199

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