Unknown

Dataset Information

0

Bis(?(2)-?:?-2,4,6-trimethyl-benzonitrile)-bis-[(N-isopropyl-3,5-dimethyl-anilido)molybdenum(III)](Mo-Mo).

ABSTRACT: The title compound, [Mo(2)(C(11)H(16)N)(4)(C(10)H(11)N)(2)], is a dinuclear molybdenum complex with a formal metal-metal bond [Mo?Mo separation = 2.5946?(8)?Å], four anilide-type ligands and two bridging mesityl nitrile groups. There are two inversion symmetric mol-ecules in the unit cell (an inversion center is localized at the mid-point of the Mo-Mo bond), each with approximate non-crystallographic C(2h) symmetry. The mol-ecules contain disordered isopropyl and 3,5-C(6)H(3)Me(2) groups on different anilido ligands; the major component having an occupancy of 0.683?(7). The complex was obtained in low yield as the product from the reaction between the bridging pyrazine adduct of molybdenum tris--anilide ([?(2)-(C(4)H(4)N(2)){Mo(C(11)H(16)N)(3)}(2)]) and mesityl nitrile with a loss of one anilido ligand.

SUBMITTER: Moroz YS 

PROVIDER: S-EPMC3238583 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Bis(μ(2)-η:η-2,4,6-trimethyl-benzonitrile)-bis-[(N-isopropyl-3,5-dimethyl-anilido)molybdenum(III)](Mo-Mo).

Moroz Yurii S YS   Cozzolino Anthony F AF   Rybak-Akimova Elena V EV   Cummins Christopher C CC  

Acta crystallographica. Section E, Structure reports online 20111102 Pt 12

The title compound, [Mo(2)(C(11)H(16)N)(4)(C(10)H(11)N)(2)], is a dinuclear molybdenum complex with a formal metal-metal bond [Mo⋯Mo separation = 2.5946 (8) Å], four anilide-type ligands and two bridging mesityl nitrile groups. There are two inversion symmetric mol-ecules in the unit cell (an inversion center is localized at the mid-point of the Mo-Mo bond), each with approximate non-crystallographic C(2h) symmetry. The mol-ecules contain disordered isopropyl and 3,5-C(6)H(3)Me(2) groups on diff  ...[more]

Similar Datasets

Unknown 2,4,6-Trimethyl-3,5-bis[(phenylcarbono-thioyl)sulfanylmethyl]benzyl benzenecarbodithioate.
| S-EPMC2979543 | biostudies-literature
Unknown 1-[2,4,6-Trimethyl-3,5-bis-(4-oxopiperidin-1-ylmeth-yl)benz-yl]piperidin-4-one.
| S-EPMC2979355 | biostudies-literature
Unknown Bis(2,4,6-trimethyl-pyridinium) hexa-chloridoplatinate(IV).
| S-EPMC2959317 | biostudies-literature
Unknown Bis(2,4,6-trimethyl-phen-yl)zinc(II).
| S-EPMC2969329 | biostudies-literature
Unknown Bis{?-N-[(dimethyl-amino)-dimethyl-sil-yl]-2,6-dimethyl-anilido}-?N:N';?N':N-dicopper(I).
| S-EPMC3009272 | biostudies-literature
Unknown Bis(4-cyano-phenolato)[hydro-tris-(3,5-dimethyl-pyrazol-yl)borato]nitro-syl-molybdenum(II)-4-hydroxy-benzonitrile-dichloro-methane (1/1/1).
| S-EPMC3011797 | biostudies-other
Unknown Bis(μ-diethyl-phosphido-κP:P)bis-[bis(2,4,6-trimethyl-phen-yl)indium(III)].
| S-EPMC3246993 | biostudies-literature
Unknown Bis(2,4,6-trimethyl-anilinium) sulfate monohydrate.
| S-EPMC3201497 | biostudies-other
Unknown Bis(2,4,6-trimethyl-pyridinium) tetra-bromidozincate.
| S-EPMC3515090 | biostudies-other
Unknown Bis(3-methyl-phenolato-κO)(nitros-yl-κN)[tris-(3,5-dimethyl-pyrazol-1-yl-κN)hydridoborato]molybdenum(II).
| S-EPMC2983427 | biostudies-literature