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Dicarbon-yl(?-cyclo-penta-dien-yl)bis-(trimethyl-phosphine)molybdenum(II) trifluoro-methane-sulfonate.

ABSTRACT: In the title compound, [Mo(C(5)H(5))(CO)(2)(C(3)H(9)P)(2)]CF(3)SO(3), the cationic complex displays a classical four-legged piano-stool square-pyramidal geometry with a trans configuration of the basal ligands around the Mo atom. The cyclo-penta-dienyl (Cp) ligand occupies the apical position of the piano-stool configuration. The average Mo-P bond length of the two trans PMe(3) ligands is 2.474?(5)?Å and the Mo-Cp centroid distance is 2.003?(2)?Å.

SUBMITTER: Jali S

PROVIDER: S-EPMC2959586 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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Dicarbon-yl(η-cyclo-penta-dien-yl)bis-(trimethyl-phosphine)molybdenum(II) trifluoro-methane-sulfonate.

Jali Samuel S Friedrich Holger B HB Bala Muhammad D MD

Acta crystallographica. Section E, Structure reports online 20081015 Pt 11

In the title compound, [Mo(C(5)H(5))(CO)(2)(C(3)H(9)P)(2)]CF(3)SO(3), the cationic complex displays a classical four-legged piano-stool square-pyramidal geometry with a trans configuration of the basal ligands around the Mo atom. The cyclo-penta-dienyl (Cp) ligand occupies the apical position of the piano-stool configuration. The average Mo-P bond length of the two trans PMe(3) ligands is 2.474 (5) Å and the Mo-Cp centroid distance is 2.003 (2) Å. ...[more]

PMID: 21580851

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