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Bis(2,4,6-trimethyl-pyridinium) hexa-chloridoplatinate(IV).

ABSTRACT: The asymmetric unit of the title compound, (C(8)H(12)N)(2)[PtCl(6)], contains one independent protonated 2,4,6-trimethyl-pyridinium cation and one half of a centrosymmetric [PtCl(6)](2-) anion. The Pt ion has an almost ideal octa-hedral coordination. In the crystal structure, intra-molecular N-H?Cl and inter-molecular C-H?Cl hydrogen bonds result in the formation of a supra-molecular structure.

SUBMITTER: Kalateh K

PROVIDER: S-EPMC2959317 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

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Bis(2,4,6-trimethyl-pyridinium) hexa-chloridoplatinate(IV).

Kalateh Khadijeh K Ebadi Amin A Abedi Anita A Amani Vahid V Khavasi Hamid Reza HR

Acta crystallographica. Section E, Structure reports online 20080913 Pt 10

The asymmetric unit of the title compound, (C(8)H(12)N)(2)[PtCl(6)], contains one independent protonated 2,4,6-trimethyl-pyridinium cation and one half of a centrosymmetric [PtCl(6)](2-) anion. The Pt ion has an almost ideal octa-hedral coordination. In the crystal structure, intra-molecular N-H⋯Cl and inter-molecular C-H⋯Cl hydrogen bonds result in the formation of a supra-molecular structure. ...[more]

PMID: 21201020

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