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Tetra-aqua-bis-[3-(pyridin-4-yl)benzoato-?N]cobalt(II).

ABSTRACT: In the title compound, [Co(C(12)H(8)NO(2))(2)(H(2)O)(4)], the Co atom lies on a twofold rotation axis and has an N(2)O(4) octa-hedral coordination environment formed by four O atoms of water mol-ecules in the equatorial plane and two apical N atoms of pyridine groups. An intricate three-dimensional supra-molecular network is formed by multiple O-H?O hydrogen bonds between the coordinated water mol-ecules and the uncoordinated carboxyl-ate groups.

SUBMITTER: Wang HR

PROVIDER: S-EPMC3238651 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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Tetra-aqua-bis-[3-(pyridin-4-yl)benzoato-κN]cobalt(II).

Wang Hai-Rong HR Li Guo-Ting GT

Acta crystallographica. Section E, Structure reports online 20111112 Pt 12

In the title compound, [Co(C(12)H(8)NO(2))(2)(H(2)O)(4)], the Co atom lies on a twofold rotation axis and has an N(2)O(4) octa-hedral coordination environment formed by four O atoms of water mol-ecules in the equatorial plane and two apical N atoms of pyridine groups. An intricate three-dimensional supra-molecular network is formed by multiple O-H⋯O hydrogen bonds between the coordinated water mol-ecules and the uncoordinated carboxyl-ate groups. ...[more]

PMID: 22199542

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