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Bis(pentane-2,4-dionato-?O,O')(1,10-phenanthroline-?N,N')cobalt(II).

ABSTRACT: In the title compound, [Co(C(5)H(7)O(2))(2)(C(12)H(8)N(2))], the Co(II) cation lies on a twofold rotation axis and is coordinated by four O atoms from two acetyl-acetonate (acac) ligands and two N atoms from a 1,10-phenanthroline (phen) ligand in a slightly distorted octa-hedral environment, with Co-O bond lengths of 2.0565?(11) and 2.0641?(11)?Å and Co-N bond lengths of 2.1630?(12)?Å. In the crystal, there are no significant hydrogen-bonding or ?-? inter-actions.

SUBMITTER: Perdih F

PROVIDER: S-EPMC3238622 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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Bis(pentane-2,4-dionato-κO,O')(1,10-phenanthroline-κN,N')cobalt(II).

Perdih Franc F

Acta crystallographica. Section E, Structure reports online 20111105 Pt 12

In the title compound, [Co(C(5)H(7)O(2))(2)(C(12)H(8)N(2))], the Co(II) cation lies on a twofold rotation axis and is coordinated by four O atoms from two acetyl-acetonate (acac) ligands and two N atoms from a 1,10-phenanthroline (phen) ligand in a slightly distorted octa-hedral environment, with Co-O bond lengths of 2.0565 (11) and 2.0641 (11) Å and Co-N bond lengths of 2.1630 (12) Å. In the crystal, there are no significant hydrogen-bonding or π-π inter-actions. ...[more]

PMID: 22199513

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