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Chlorido(pentane-2,4-dionato-?O,O')(1,10-phenanthroline-?N,N')copper(II).

ABSTRACT: The Cu(II) atom in the title compound, [Cu(C(5)H(7)O(2))Cl(C(12)H(8)N(2))], shows a distorted square-planar coordination; the chelating N and O atoms occupy the basal sites and the Cl atom the apical site. The square-pyramidal character along the Berry D(3h)-C(4v) pseudorotation pathway is 92%.

SUBMITTER: Wong YS

PROVIDER: S-EPMC2977398 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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Chlorido(pentane-2,4-dionato-κO,O')(1,10-phenanthroline-κN,N')copper(II).

Wong Yew Sent YS Ng Chew Hee CH Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20090718 Pt 8

The Cu(II) atom in the title compound, [Cu(C(5)H(7)O(2))Cl(C(12)H(8)N(2))], shows a distorted square-planar coordination; the chelating N and O atoms occupy the basal sites and the Cl atom the apical site. The square-pyramidal character along the Berry D(3h)-C(4v) pseudorotation pathway is 92%. ...[more]

PMID: 21583387

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