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Poly[penta-kis-(?-cyanido-?N:C)tris-(5-phenyl-2,2'-bipyridine-?N,N')penta-copper(I)].

ABSTRACT: The hydro-thermal reaction of Cu(acetate)(2) and K(3)[Fe(CN)(6)] with 5-phenyl-2,2'-bipyridine (5-ph-2,2'-bpy) in water yields the polymeric title complex, [Cu(5)(CN)(5)(C(16)H(12)N(2))(3)](n), which consists of ribbons along the a axis, constructed from 26-membered {Cu(10)(CN)(8)} rings. In these rings, the metal atoms are bridged by cyanide groups, except for one close Cu?Cu contact [2.7535?(12)?Å], which can be considered as ligand-unsupported. Within the rings, one Cu atom has a distorted tetra-hedral geometry through the coordination to two N atoms from 5-ph-2,2'-bpy and two N/C atoms from two cyanide groups. Two Cu atoms have a trigonal planar environment being coordinated by three cyanide groups and two other Cu atoms have a distorted square planar geometry through coordination to two N atoms from 5-ph-2,2'-bpy and two N/C atoms from two cyanide groups.

SUBMITTER: Cui S

PROVIDER: S-EPMC3238629 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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Poly[penta-kis-(μ-cyanido-κN:C)tris-(5-phenyl-2,2'-bipyridine-κN,N')penta-copper(I)].

Cui Shuxin S Zuo Minghui M Zhang Jingping J Zhao Yulong Y Tan Rongxin R Liu Shujuan S Su Shuangyue S

Acta crystallographica. Section E, Structure reports online 20111109 Pt 12

The hydro-thermal reaction of Cu(acetate)(2) and K(3)[Fe(CN)(6)] with 5-phenyl-2,2'-bipyridine (5-ph-2,2'-bpy) in water yields the polymeric title complex, [Cu(5)(CN)(5)(C(16)H(12)N(2))(3)](n), which consists of ribbons along the a axis, constructed from 26-membered {Cu(10)(CN)(8)} rings. In these rings, the metal atoms are bridged by cyanide groups, except for one close Cu⋯Cu contact [2.7535 (12) Å], which can be considered as ligand-unsupported. Within the rings, one Cu atom has a distorted te ...[more]

PMID: 22199520

Similar Datasets

Tris(2,2'-bipyridine)-copper(II) penta-cyanido-nitro-soferrate(II) methanol disolvate monohydrate.

Project description:The title complex [Cu(C10H8N2)3][Fe(CN)5(NO)]·2CH3OH·H2O, consists of discrete [Cu(bpy)3](2+) cations (bpy is 2,2'-bipyridine), [Fe(CN)5NO](2-) anions and solvent mol-ecules of crystallization (two methanol mol-ecules and one water mol-ecules per asymmetric unit). The Cu(II) ion adopts a distorted octa-hedral environment, coordinated by six N atoms from three bpy ligands. The cation charge is balanced by a nitro-prusside counter-anion, which has a slightly distorted octa-hedral coordination geometry. In the crystal, anions and solvent mol-ecules are involved in O-H⋯N and O-H⋯O hydrogen bonds, which form chains along [100]. The cations are located between these chains.

| S-EPMC3629489 | biostudies-literature

catena-Poly[{μ-cyanido-bis-[(4,4'-dimethyl-2,2'-bipyridine-κN,N')copper(I)]}-μ-cyanido-copper(I)-μ-cyanido].

Project description:In the title compound, [Cu(3)(CN)(3)(C(12)H(12)N(2))(2)], two 2,2'-bipyridine N,N'-chelated Cu(I) atoms are linked by a cyanide bridge that lies about a center of inversion; the Cu(I) atom exists in a tetra-hedral coordination geometry. This dinuclear entity is linked to another Cu(I) atom that lies on a twofold rotation axis by another cyanide bridge, these bridges giving rise to the formation of a linear chain motif.

| S-EPMC2961986 | biostudies-literature

catena-Poly[[(5-phenyl-2,2'-bipyridine-?N,N')copper(I)]-?-thio-cyanido-?N:S].

Project description:The title compound, [Cu(NCS)(C(16)H(12)N(2))](n), was synthesised under hydro-thermal conditions. The Cu(I) ion shows distorted tetra-hedral geometry being coordinated by two N atoms from a 5-phenyl-2,2'-bipyridine ligand and by the N and S atoms from two different thio-cyanate anions. The Cu(I) ions are bridged by thio-cyanide groups, forming a one-dimensional coordination polymer along the b axis. The crystal packing is through van der Waals contacts and C-H?? inter-actions.

| S-EPMC3274895 | biostudies-other

catena-Poly[[(2,2'-bipyridine-κN,N')copper(I)]-μ-cyanido-κC:N-[(2,2'-bipyridine-κN,N')copper(I)]-μ-thio-cyanato-κS:N].

Project description:The title compound, [Cu(2)(CN)(SCN)(C(10)H(8)N(2))(2)](n), contains two crystallographically independent Cu(I) atoms, each in a distorted tetra-hedral geometry. Each Cu atom is coordinated by a bidentate chelating 2,2'-bipyridine ligand. A bridging cyanide anion links the two Cu(2,2'-bipyridine) units to form a binuclear unit. Adjacent binuclear units are connected by a thio-cyanate anion into a one-dimensional helical chain along [010]. The cyanide anion is disordered, with each site occupied by both C and N atoms in an occupancy ratio of 0.61 (5):0.39 (5). The S atom of the thio-cyanate anion is also disordered over two sites, with occupancy factors of 0.61 (3) and 0.39 (3). There are π-π inter-actions between the pyridyl rings of neighbouring chains [centroid-centroid distance = 3.82 (1) Å].

| S-EPMC2959861 | biostudies-literature

Tris(2,2'-bipyridine-?N,N')cobalt(III) octa-cyanido-tungstate(V).

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Poly[diaqua-bis(2,2'-bipyridine)tris-(μ(4)-2,2'-bipyridine-4,4'-dicarboxyl-ato)dineodymium(III)].

Project description:In the crystal structure of the title mixed-ligand coordination polymer, [Nd(2)(C(12)H(6)N(2)O(4))(3)(C(10)H(8)N(2))(2)(H(2)O)(2)](n), the Nd(III) ion is in an octa-hedral coordination environment formed by one water mol-ecule, one chelating 2,2'-bipyridine ligand, and five monodentate carboxyl-ate groups. The local coordination polyhedron around the Nd(III) ion is a bicapped trigonal prism. Two Nd(III) centers are bridged by four carboxyl-ate groups to form an Nd(2) dimeric unit; these are further connected by 2,2'-bipyridine-4,4'-dicarboxyl-ate linkers, resulting in a layered coordination network.

| S-EPMC2915173 | biostudies-literature

catena-Poly[[(2,2'-bipyridine)copper(II)]-μ-5-tert-butyl-isophthalato].

Project description:In the crystal structure of the title polymeric compound, [Cu(C(12)H(12)O(4))(C(10)H(8)N(2))](n), the asymmetric unit consists of one Cu(II) ion, one 5-tert-butyl-isophthalate (tbip) and one 2,2'-bipyridine (bpy) ligand. The copper(II) ion is four-coordin-ated by two N atoms from bipy and two O atoms from two tbip ligands, leading to a distorted tetrahedral coordination. Each tbip ligand adopts a bis-monodentate coordination mode to connect two symmetry-related copper(II) ions, so forming a zigzag polymer chain parallel to [001]. The tert-butyl methyl groups are disordered over two positions with occupancies of 0.506 (6)/0.494 (6).

| S-EPMC2960003 | biostudies-literature

catena-poly[[[(2,2'-bipyridine-2κN,N')-μ-cyanido-1:2κN:C-cyanido-2κC-tris-(methanol-1κO)(nitrato-1κO,O')iron(II)yttrium(III)]-di-μ-cyanido-1:2'κN:C;2:1'κC:N] methanol solvate hemihydrate].

Project description:The title complex, {[Fe(II)Y(III)(CN)(4)(NO(3))(C(10)H(8)N(2))(CH(3)OH)(3)]·CH(3)OH·0.5H(2)O}(n), is built up of ladder-like chains oriented along the c axis. Each ladder consists of two strands based on alternating Fe(II) and Y(III) ions connected by cyanide bridges. Two such parallel chains are connected by additional cyanide anions (the 'rungs' of the ladder), which likewise connect Fe(II) and Y(III) ions, such that each [Fe(bipy)(CN)(4)](2-) (bipy is 2,2'-bipyridine) unit coordinates with three Y(III) ions and each Y(III) ion connects with three different [Fe(bipy)(CN)(4)](2-) units. The Fe(II) atom is six-coordinated in a distorted octa-hedral geometry and the Y(III) atom cation is eight-coordinated in a distorted dodeca-hedral environment. The uncoordinated methanol solvent mol-ecules are involved in hydrogen-bonding inter-actions with the one terminal cyanide group and a coordinated methanol mol-ecule from another [Y(III)(NO(3))(CH(3)OH)(3)](2+) unit. Adjacent ladder-like chains are also held together by hydrogen bonds between the terminal cyanide ligands of the [Fe(CN)(4)(bipy)](2-) units in one chain and the OH donors of CH(3)OH ligands from [Y(III)(NO(3))(CH(3)OH)(3)] units in neighboring chains. The water molecule exhibits half-occupation.

| S-EPMC3007586 | biostudies-literature

(Cyanido-κC)(2,2-di-phenyl-acetamido-κ(2) N,O)bis-(η(5)-penta-methyl-cyclo-penta-dien-yl)zirconium(IV).

Project description:In the title compound, [Zr(C10H15)2(C14H12NO)(CN)], the Zr(IV) atom is coordinated by two penta-methyl-cyclo-penta-dienyl ligands, the amidate ligand via the N and O atoms, and an additional C N ligand. The four-membered metallacycle is nearly planar (r.m.s. deviation = 0.008 Å). In the crystal, the mol-ecules are connected into centrosymmetric dimers via pairs of N-H⋯N hydrogen bonds.

| S-EPMC3998262 | biostudies-literature

catena-Poly[[(3-methyl-pyridine)-copper(I)]-?-cyanido-copper(I)-?-cyanido].

Project description:In the title complex, [Cu(2)(CN)(2)(C(6)H(7)N)](n), there are two copper atoms with different coordination environments. One Cu atom (Cu1) is linked to the two cyanide ligands, one N atom from a pyridine ring while the other (Cu2) is coordinated by the two cyanide ligands in a slightly distorted tetra-hedral geometry and linked to Cu1, forming a triangular coordination environment. The Cu atoms are bridged by bidentate cyanide ligands, forming an infinite Cu-CN chain. One cyanide ligand is equally disordered over two sets of sites, exchanging C and N atoms coordinated to both metal atoms. However, one cyanide group is not disordered and it coordinates to Cu1 via the N atom whereas its C-atom counterpart coordinates Cu2. The 3-methyl-pyridine (3MP) ligand coordinates through the N atom to Cu1 as a terminal ligand, which originates from decyanation of 3-pyridyl-acetonitrile under hydro-thermal conditions. Adjacent Cu-CN chains are inter-connected through Cu?Cu inter-actions [2.8364?(10)?Å], forming a three-dimensional framework.

| S-EPMC3212195 | biostudies-literature

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