Ontology highlight
ABSTRACT:
SUBMITTER: Cui S
PROVIDER: S-EPMC3238629 | biostudies-literature | 2011 Dec
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20111109 Pt 12
The hydro-thermal reaction of Cu(acetate)(2) and K(3)[Fe(CN)(6)] with 5-phenyl-2,2'-bipyridine (5-ph-2,2'-bpy) in water yields the polymeric title complex, [Cu(5)(CN)(5)(C(16)H(12)N(2))(3)](n), which consists of ribbons along the a axis, constructed from 26-membered {Cu(10)(CN)(8)} rings. In these rings, the metal atoms are bridged by cyanide groups, except for one close Cu⋯Cu contact [2.7535 (12) Å], which can be considered as ligand-unsupported. Within the rings, one Cu atom has a distorted te ...[more]