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3-Butyl-1-methyl-1H-imidazol-3-ium bis-(1,2-dicyano-ethene-1,2-dithiol-ato-?S,S')nickel(III).

ABSTRACT: In the title compound, (C(8)H(15)N(2))[Ni(C(4)N(2)S(2))(2)], the Ni(III) atom is coordinated by four S atoms of two maleonitrile-dithiol-ate ligands and exhibits a distorted square-planar geometry. In the crystal, the cations and anions are connected alternately by weak inter-molecular C-H?N hydrogen bonds, forming a zigzag chain along [201].

SUBMITTER: Yu SS

PROVIDER: S-EPMC3238640 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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3-Butyl-1-methyl-1H-imidazol-3-ium bis-(1,2-dicyano-ethene-1,2-dithiol-ato-κS,S')nickel(III).

Yu Shan-Shan SS

Acta crystallographica. Section E, Structure reports online 20111109 Pt 12

In the title compound, (C(8)H(15)N(2))[Ni(C(4)N(2)S(2))(2)], the Ni(III) atom is coordinated by four S atoms of two maleonitrile-dithiol-ate ligands and exhibits a distorted square-planar geometry. In the crystal, the cations and anions are connected alternately by weak inter-molecular C-H⋯N hydrogen bonds, forming a zigzag chain along [201]. ...[more]

PMID: 22199531

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