Browse
Submit Data
Databases
API
Help

Dataset Information

48 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

1-Butyl-pyridinium bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(III).

ABSTRACT: The Ni(III) atom in the anion of the title complex, (C(9)H(14)N)[Ni(C(4)N(2)S(2))(2)], is coordinated by four S atoms of two maleonitrile-dithiol-ate ligands, and exhibits a square-planar coordination geometry.

SUBMITTER: Duan HB

PROVIDER: S-EPMC3246985 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

1-Butyl-pyridinium bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(III).

Duan Hai-Bao HB

Acta crystallographica. Section E, Structure reports online 20111022 Pt 11

The Ni(III) atom in the anion of the title complex, (C(9)H(14)N)[Ni(C(4)N(2)S(2))(2)], is coordinated by four S atoms of two maleonitrile-dithiol-ate ligands, and exhibits a square-planar coordination geometry. ...[more]

PMID: 22219805

Similar Datasets

Bis[1-(3-cyano-benz-yl)pyridinium] bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II).

Project description:In the ionic title complex, (C(13)H(11)N(2))(2)[Ni(C(4)N(2)S(2))(2)], the Ni(II) ion is located on an inversion centre so the asymmetric unit contains one-half [Ni(mnt)(2)](2-) dianion (mnt(2-) is maleonitrile-dithiolate) and one 1-(3-cyano-benz-yl)pyridinium cation ([CNBzPy](+)). The Ni(II) ion in the [Ni(mnt)(2)](2-) anion is coordinated by four S atoms of two mnt(2-) ligands, and exhibits square-planar coordination geometry. In the [CNBzPy](+) cation, the benzene and pyridine rings are twisted with respect to the C/C/N plane incorporating the methyl-ene C atom that links them. The crystal structure is stabilized by Coulombic inter-actions.

| S-EPMC3050285 | biostudies-literature

1-(2-Fluoro-benzyl-ideneamino)pyridinium bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II).

Project description:In the title complex, (C(12)H(10)FN(2))(2)[Ni(C(4)N(2)S(2))(2)], the anion lies on an inversion center with the Ni(II) ion coordinated by four S atoms in a slightly distorted square-planar environment. In the unique cation, the dihedral angle between the benzene and pyridine rings is 7.1 (2) Å.

| S-EPMC2977634 | biostudies-literature

Bis(1-amino-4-methyl-pyridinium) bis-(1,2-dicyano-ethene-1,2-dithiol-ato-κS,S')nickelate(II).

Project description:The asymmetric unit of the title compound, (C(6)H(9)N(2))(2)[Ni(C(4)N(2)S(2))(2)], contains one half of an [Ni(mnt)(2)](2-) anion (mnt is maleonitrile-dithiol-ate or 1,2-dicyano-ethene-1,2-dithiol-ate) and one 1-amino-4-methyl-pyridinium cation. The Ni(II) atom is located on an inversion centre. In the crystal structure, inter-molecular N-H⋯N hydrogen bonds link the mol-ecules.

| S-EPMC2961888 | biostudies-literature

Bis(4-dimethyl-amino-1-ethyl-pyridinium) bis-(1,2-dicyano-ethene-1,2-dithiol-ato-κ(2)S,S')nickelate(II).

Project description:The asymmetric unit of the title complex, (C(9)H(15)N(2))(2)[Ni(C(4)N(2)S(2))(2)], comprises one 4-dimethyl-amino-1-ethyl-pyri-din-ium cation and one half of a [Ni(mnt)(2)](2-) (mnt(2-) = maleo-nitrile-dithiol-ate) anion; the complete anion is generated by the application of a centre of inversion. The Ni(II) ion is coordinated by four S atoms of two mnt(2-) ligands and exhibits a square-planar coordination geometry.

| S-EPMC3343807 | biostudies-literature

Bis[1-(eth-oxy-carbonyl-meth-yl)pyridinium] bis-(1,2-dicyano-ethene-1,2-dithiol-ato-κ(2)S,S')nickelate(II).

Project description:The asymmetric unit of the title ion-pair complex, (C(9)H(12)NO(2))(2)[Ni(C(4)N(2)S(2))(2)], contains two 1-(eth-oxy-carbonyl-meth-yl)pyridinium cations and one bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II) dianion, which exhibits a slightly distorted square-planar coordination geometry. In the crystal, the cations are linked by strong C-H⋯O hydrogen bonds into C(6) chains along [100]. The cations and anions are linked into a three-dimensional architecture by weak C-H⋯N and C-H⋯S inter-actions.

| S-EPMC3435580 | biostudies-literature

Bis[1-(4-cyano-benz-yl)pyrazinium] bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II).

Project description:The asymmetric unit of the title complex, (C(12)H(10)N(3))(2)[Ni(C(4)N(2)S(2))(2)], consists of one 1-(4-cyano-benz-yl)pyrazinium cation and one half of an [Ni(mnt)(2)](2-) dianion (mnt(2-) is 1,2-dicyano-ethene-1,2-dithiol-ate). The Ni(2+) ion is located on an inversion center and is coordinated by four S atoms from two mnt(2-) ligands, exhibiting a square-planar coordination geometry. The cation adopts a conformation where both the pyrazine ring and the benzene ring are twisted with respect to the C-C-N reference plane by 16.5 (2) and 69.8 (1)°, respectively.

| S-EPMC3152075 | biostudies-literature

Bis(3,5,7-triaza-1-azoniatricyclo-[3.3.1.1]deca-ne) bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II).

Project description:The asymmetric unit of the title complex, (C(6)H(13)N(4))(2)[Ni(C(4)N(2)S(2))(2)], comprises one 1-azonia-3,5,7-triaza-tricyclo-[3.3.1.1(3,7)]decane cation and one half of an [Ni(mnt)(2)](2-) (mnt(2-) is maleonitrile-dithiol-ate or 1,2-dicyano-ethene-1,2-dithiol-ate) dianion. The Ni(2+) ion is located on a center of inversion and is coordinated by four S atoms from two mnt(2-) ligands in a square-planar coordination mode. Inter-molecular N-H⋯N hydrogen-bond inter-actions link one anion and two cations in the crystal structure.

| S-EPMC3120553 | biostudies-literature

Bis(4-cyano-1-methyl-pyridinium) bis-(1,2-dicyano-ethene-1,2-dithiol-ato-κS,S')cuprate(II).

Project description:The title ion-pair compound, (C(7)H(7)N(2))(2)[Cu(C(4)N(2)S(2))(2)], was obtained by the direct reaction of CuCl(2)·2H(2)O, disodium maleonitrile-dithiol-ate (Na(2)mnt) and 4-cyano-1-methyl-pyridinium iodide. The anion and one pyridinium cation lie entirely on a mirror plane, whereas for the other cation, a crystallographic mirror plane runs through the N and para-C atoms of the pyridine ring, the methyl C atom, and the cyano group. In the crystal, ions are linked into a three-dimensional network by C-H⋯N hydrogen bonds.

| S-EPMC3274894 | biostudies-literature

3-Butyl-1-methyl-1H-imidazol-3-ium bis-(1,2-dicyano-ethene-1,2-dithiol-ato-κS,S')nickel(III).

Project description:In the title compound, (C(8)H(15)N(2))[Ni(C(4)N(2)S(2))(2)], the Ni(III) atom is coordinated by four S atoms of two maleonitrile-dithiol-ate ligands and exhibits a distorted square-planar geometry. In the crystal, the cations and anions are connected alternately by weak inter-molecular C-H⋯N hydrogen bonds, forming a zigzag chain along [201].

| S-EPMC3238640 | biostudies-literature

Bis(8-hy-droxy-1-methyl-quinolin-1-ium) bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II) dihydrate.

Project description:In the title ion-pair complex, (C(10)H(10)NO)(2)[Ni(C(4)N(2)S(2))(2)]·2H(2)O, the anion has crystallographically imposed centre of symmetry. The Ni(II) atom exhibits a slightly distorted square-planar coordination geometry. In the crystal, the water mol-ecule links anions and cations into a three-dimensional network via O-H⋯N, O-H⋯S and O-H⋯O hydrogen bonds. The structure is further stabilized by weak S⋯π contacts [S⋯centroid = 3.8047 (9) Å] and π-π stacking inter-actions [centriod-centroid distance = 3.8653 (7) Å].

| S-EPMC3238595 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data