Unknown

Dataset Information

0

Catena-Poly[[[bis-(methanol-?O)lead(II)]-?-N'-[1-(pyridin-2-yl-?N)ethyl-idene]isonicotinohydrazidato-?N',O:N] perchlorate].

ABSTRACT: The Pb(II) atom in the polymeric title compound, {[Pb(C(13)H(11)N(4)O)(CH(3)OH)(2)]ClO(4)}(n), is coordinated by an N'-[1-(pyridin-2-yl-?N)ethyl-idene]isonicotinohydrazidate ligand via O,N,N'-donors and simultaneously bridged by a neighbouring ligand via the isonicotinoyl N atom; two additional sites are occupied by methanol O atoms. The resultant supra-molecular chain is a zigzag along the c axis. The Pb(II) atom is seven-coordinated within an N(3)O(3) donor set and a lone pair of electrons, which defines a ?-pentagonal-bipyramidal coordination geometry with the pyridine N and lone pair in axial positions. The supra-molecular chains are linked into the two-dimensional array via inter-molecular Pb?N [3.020?(4)?Å] inter-actions. Layers stack along the a axis, being connected by O-H?O hydrogen bonds formed between the coordinated methanol mol-ecules and perchlorate anions.

SUBMITTER: Shahverdizadeh GH 

PROVIDER: S-EPMC3238642 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

catena-Poly[[[bis-(methanol-κO)lead(II)]-μ-N'-[1-(pyridin-2-yl-κN)ethyl-idene]isonicotinohydrazidato-κN',O:N] perchlorate].

Shahverdizadeh Gholam Hossein GH   Tiekink Edward R T ER   Mirtamizdoust Babak B  

Acta crystallographica. Section E, Structure reports online 20111109 Pt 12

The Pb(II) atom in the polymeric title compound, {[Pb(C(13)H(11)N(4)O)(CH(3)OH)(2)]ClO(4)}(n), is coordinated by an N'-[1-(pyridin-2-yl-κN)ethyl-idene]isonicotinohydrazidate ligand via O,N,N'-donors and simultaneously bridged by a neighbouring ligand via the isonicotinoyl N atom; two additional sites are occupied by methanol O atoms. The resultant supra-molecular chain is a zigzag along the c axis. The Pb(II) atom is seven-coordinated within an N(3)O(3) donor set and a lone pair of electrons, wh  ...[more]

Similar Datasets

Unknown catena-Poly[[lead(II)-?-N'-[1-(pyridin-2-yl-?N)ethyl-idene]isonicotino-hydrazidato-?N',O:N] perchlorate].
| S-EPMC3238641 | biostudies-literature
Unknown catena-Poly[[(nitrito-?O,O')silver(I)]-?-1,2-bis-[1-(pyridin-4-yl)ethyl-idene]hydrazine-?N:N'].
| S-EPMC3212196 | biostudies-literature
Unknown Bis{N-methyl-N'-[1-(pyridin-2-yl)ethyl-idene]ethane-1,2-diamine}-zinc bis-(perchlorate).
| S-EPMC3212129 | biostudies-literature
Unknown catena-Poly[[(triphenyl-phosphane)copper(I)]-di-?-iodido-[(triphenyl-phosphane)copper(I)]-?-{1,2-bis-[1-(pyridin-4-yl)ethyl-idene]hydrazine}].
| S-EPMC3201507 | biostudies-literature
Unknown catena-Poly[[[bis-(methanol-?O)bis-(seleno-cyanato-?N)manganese(II)]-?-1,2-bis-(pyridin-4-yl)ethane-?(2) N:N'] 1,2-bis-(pyridin-4-yl)ethane monosolvate].
| S-EPMC3629498 | biostudies-literature
Unknown catena-Poly[[[di-aqua-bis-[1,2-bis-(pyridin-4-yl)diazene]copper(II)]-?-1,2-bis-(pyridin-4-yl)diazene] bis-(perchlorate)].
| S-EPMC3684881 | biostudies-other
Unknown catena-Poly[(dichloridozinc)-?-bis-(pyridin-3-yl)methanone-?N:N'].
| S-EPMC3238669 | biostudies-literature
Unknown catena-Poly[[[bis-(methanol-?O)bis-(seleno-cyanato-?N)manganese(II)]-?-1,2-bis-(pyridin-4-yl)eth-ene-?(2) N:N'] 1,2-bis-(pyridin-4-yl)eth-ene mono-solvate].
| S-EPMC3684882 | biostudies-literature
Unknown catena-Poly[[copper(II)-bis[?-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(perchlorate)].
| S-EPMC2971148 | biostudies-literature
Unknown catena-Poly[[[(3,5-dimethyl-1H-pyrazole)-copper(II)]-?-{N-[1-(2-oxidophen-yl)ethyl-idene]-l-valinato}] methanol monosolvate].
| S-EPMC3051769 | biostudies-literature