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Bis[N-(pyridin-2-ylcarbon-yl)pyridine-2-carboximidato-?N,N',N'']iron(III) tris-(cyanido-?C)[N-(pyridin-2-ylcarbon-yl)pyridine-2-carboximidato-?N,N',N'']ferrate(III) monohydrate.

ABSTRACT: In the title compound, [Fe(C(12)H(8)N(3)O(2))(2)][Fe(C(12)H(8)N(3)O(2))(CN)(3)]·H(2)O, the Fe(3+) ions in the cation and anion each lie in a slightly distorted octa-hedral coordination environment. The solvent water mol-ecule is disordered over three positions with occupancies of 0.401?(7), 0.322?(7) and 0.277?(6). The water content was confirmed by thermogravimetric data.

SUBMITTER: Xiao Y

PROVIDER: S-EPMC3238645 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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Bis[N-(pyridin-2-ylcarbon-yl)pyridine-2-carboximidato-κN,N',N'']iron(III) tris-(cyanido-κC)[N-(pyridin-2-ylcarbon-yl)pyridine-2-carboximidato-κN,N',N'']ferrate(III) monohydrate.

Xiao Yunyun Y Shen Xiaoping X Li Yizhi Y

Acta crystallographica. Section E, Structure reports online 20111109 Pt 12

In the title compound, [Fe(C(12)H(8)N(3)O(2))(2)][Fe(C(12)H(8)N(3)O(2))(CN)(3)]·H(2)O, the Fe(3+) ions in the cation and anion each lie in a slightly distorted octa-hedral coordination environment. The solvent water mol-ecule is disordered over three positions with occupancies of 0.401 (7), 0.322 (7) and 0.277 (6). The water content was confirmed by thermogravimetric data. ...[more]

PMID: 22199536

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