Unknown

Dataset Information

0

Crystal structure of 4-{(E)-[2-(pyridin-4-ylcarbon-yl)hydrazin-1-yl-idene]meth-yl}phenyl acetate monohydrate.

ABSTRACT: The asymmetric unit of the title compound, C15H13N3O3·H2O, comprises a 4-{(E)-[2-(pyridin-4-ylcarbon-yl)hydrazinyl-idene]meth-yl}phenyl acetate mol-ecule and a solvent water mol-ecule linked by O-H?O and O-H?N hydrogen bonds from the water mol-ecule and a C-H?O contact from the organic mol-ecule. The compound adopts an E conformation with respect to the azomethine bond and the dihedral angle between the pyridine and benzene rings is 21.90?(7)°. The azomethine bond [1.275?(2)?Å] distance is very close to the formal C=N bond length, which confirms the azomethine bond formation. An extensive set of O-H?O, O-H?N, N-H?O and C-H?O hydrogen bonds builds a two-dimensional network progressing along the c axis.

SUBMITTER: Datta R 

PROVIDER: S-EPMC4384571 | biostudies-literature | 2015 Feb

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Crystal structure of 4-{(E)-[2-(pyridin-4-ylcarbon-yl)hydrazin-1-yl-idene]meth-yl}phenyl acetate monohydrate.

Datta Riya R   Ramya V V   Sithambaresan M M   Kurup M R Prathapachandra MR  

Acta crystallographica. Section E, Crystallographic communications 20150103 Pt 2

The asymmetric unit of the title compound, C15H13N3O3·H2O, comprises a 4-{(E)-[2-(pyridin-4-ylcarbon-yl)hydrazinyl-idene]meth-yl}phenyl acetate mol-ecule and a solvent water mol-ecule linked by O-H⋯O and O-H⋯N hydrogen bonds from the water mol-ecule and a C-H⋯O contact from the organic mol-ecule. The compound adopts an E conformation with respect to the azomethine bond and the dihedral angle between the pyridine and benzene rings is 21.90 (7)°. The azomethine bond [1.275 (2) Å] distance is very  ...[more]

Similar Datasets

Unknown 4-{(E)-[2-(Pyridin-3-ylcarbon-yl)hydrazinyl-idene]meth-yl}phenyl acetate.
| S-EPMC3790414 | biostudies-literature
Unknown Crystal structure of (pyridin-2-yl-methyl-idene)(tri-phenyl-meth-yl)amine.
| S-EPMC4257176 | biostudies-literature
Unknown (E)-1-Phenyl-2-({5-[(1E)-(2-phenyl-hydrazin-1-yl-idene)meth-yl]-2-thien-yl}methyl-idene)hydrazine.
| S-EPMC2983505 | biostudies-literature
Unknown Ethyl (Z)-2-chloro-2-(2-phenyl-hydrazin-1-yl-idene)acetate.
| S-EPMC3007979 | biostudies-literature
Unknown Crystal structure of ethyl 2-(2-{(1E)-[(E)-2-(2-hy-droxy-benzyl-idene)hydrazin-1-yl-idene]meth-yl}phen-oxy)acetate.
| S-EPMC4384580 | biostudies-literature
Unknown Bis{2-[(2-benzoyl-hydrazin-1-yl-idene)meth-yl]-6-meth-oxy-phenolato}iron(III) chloride monohydrate.
| S-EPMC3007077 | biostudies-literature
Unknown Benzoic acid-4-{(1E)-[(E)-2-(pyridin-4-yl-methyl-idene)hydrazin-1-yl-idene]meth-yl}pyridine (2/1).
| S-EPMC3009056 | biostudies-literature
Unknown Crystal structure of ethyl 2-({[(4Z)-3,5-dioxo-1-phenyl-pyrazolidin-4-yl-idene]meth-yl}amino)-acetate.
| S-EPMC4186195 | biostudies-literature
Unknown Ethyl (Z)-2-chloro-2-[2-(4-meth-oxy-phenyl)hydrazin-1-yl-idene]acetate.
| S-EPMC3588822 | biostudies-other
Unknown (E)-4-{[2-(2-Furylcarbon-yl)hydrazinyl-idene]meth-yl}-2-meth-oxy-phenyl acetate.
| S-EPMC3099912 | biostudies-literature