Browse
Submit Data
Databases
API
Help

Dataset Information

14 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

[(Z)-1-({3-[(3-Amino-prop-yl)(2-nitro-benz-yl)amino]-prop-yl}imino-meth-yl)naphthalen-2-olato]copper(II) perchlorate.

ABSTRACT: In the title compound, [Cu(C(24)H(27)N(4)O(3))]ClO(4), the Cu(II) atom has a distorted square-planar coordination geometry and is surrounded by an N(3)O donor set composed of a secondary amine N, a primary amine H, an imino N and a naphthalen-2-olate O atom. An intra-molecular N-H?O hydrogen bond occurs. In the crystal, mol-ecules are held together by inter-molecular N-H?O hydrogen bonds, leading to the formation of a three-dimensional network.

SUBMITTER: Azadbakht R

PROVIDER: S-EPMC3238655 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

[(Z)-1-({3-[(3-Amino-prop-yl)(2-nitro-benz-yl)amino]-prop-yl}imino-meth-yl)naphthalen-2-olato]copper(II) perchlorate.

Azadbakht Reza R Amiri Rudbari Hadi H Menati Saeid S Bruno Giuseppe G

Acta crystallographica. Section E, Structure reports online 20111112 Pt 12

In the title compound, [Cu(C(24)H(27)N(4)O(3))]ClO(4), the Cu(II) atom has a distorted square-planar coordination geometry and is surrounded by an N(3)O donor set composed of a secondary amine N, a primary amine H, an imino N and a naphthalen-2-olate O atom. An intra-molecular N-H⋯O hydrogen bond occurs. In the crystal, mol-ecules are held together by inter-molecular N-H⋯O hydrogen bonds, leading to the formation of a three-dimensional network. ...[more]

PMID: 22199546

Similar Datasets

[2-({Benz-yl[2-(benz-yl{5-methyl-2-oxido-3-[(pyridin-2-ylmeth-yl)imino-meth-yl]benz-yl}amino)-eth-yl]aza-nium-yl}meth-yl)-4-methyl-6-[(pyridin-2-ylmeth-yl)imino-meth-yl]phenolato]nickel(II) perchlorate methanol disolvate.

Project description:In the solvated title complex, [Ni(C(46)H(47)N(6)O(2))]ClO(4)·2CH(4)O, the coordination sphere around the Ni(II) ion can be described as distorted cis-NiO(2)N(4) octa-hedral defined by two phenolate O atoms and four N atoms from the hexa-dentate ligand. An intra-molecular bifurcated N-H?(N,O) hydrogen bond helps to establish the conformation of the complex mol-ecule. In the crystal, the components are connected by O-H?O and C-H?O hydrogen bonds.

| S-EPMC3379195 | biostudies-literature

1-{(E)-[(2-Fluoro-5-nitro-phen-yl)imino]-meth-yl}naphthalen-2-ol.

Project description:The title mol-ecule, C17H11FN2O3, is nearly planar [maximum deviation = 0.197 (1) Å] and the mol-ecular conformation is stabilized by an N-H⋯O hydrogen bond forming an S(6) ring motif. The H atom of the intra-molecular hydrogen bond was found to be disordered over two sites and thus both the hy-droxy and keto tautomers are simultaneously present in the solid. Refinement of the occupancy of this site suggests that the hy-droxy form is the major component [occupancy refined to 0.59 (3):0.41 (3)]. Bond lengths are also largely consistent with dominance of the hy-droxy form. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds, forming layers parallel to (101). π-π stacking inter-actions [centroid-centroid distances = 3.5649 (9) and 3.7579 (9) Å] inter-connect these layers.

| S-EPMC3684934 | biostudies-literature

Bis{1-[3-(diethyl-ammonio)-propyl-imino-meth-yl]naphthalen-2-olato}nickel(II) dinitrate.

Project description:The asymmetric unit of the title compound, [Ni(C(18)H(24)N(2)O)(2)](NO(3))(2), consists of one half of the centrosymmetric nickel(II) complex cation and a nitrate anion. The Ni(II) atom, lying on an inversion center, is four-coordinated by the phenolate O atoms and imine N atoms of two Schiff base ligands, forming a square-planar geometry. The O- and N-donor atoms are mutually trans. In the crystal structure, the nitrate anions are linked to the complex cations by inter-molecular N-H?O hydrogen bonds.

| S-EPMC3007399 | biostudies-literature

(E)-1-[(2-Chloro-4-nitro-phenyl-imino)-meth-yl]naphthalen-2-ol.

Project description:In the title compound, C(17)H(11)ClN(2)O(3), an intra-molecular O-H⋯N hydrogen bond influences the mol-ecular conformation; the naphthol system and the substituted benzene ring form a dihedral angle of 3.5 (1)°. In the crystal, weak inter-molecular C-H⋯O hydrogen bonds link mol-ecules into chains in the [010] direction The crystal packing exhibits π-π inter-actions between the aromatic rings from the neighbouring mol-ecules, with a centroid-centroid distance of 3.566 (7) Å.

| S-EPMC3151923 | biostudies-literature

[2-({3-[(3-Amino-prop-yl)amino]-prop-yl}imino-meth-yl)phenolato-?O,N,N'',N''']bromidocopper(II).

Project description:In the title compound, [Cu(C(13)H(20)N(3)O)Br], the Cu(II) atom is coordinated by three N atoms and one O atom from the deprotonated ligand derived from the Schiff base condensation of 3,3-imino-bis-(propyl-amine) and salicyl-aldehyde. The three N and the O atoms occupy equatorial positions, while the Br atom occupies an axial position. The amine H atoms form inter-molecular hydrogen bonds with the Br and O atoms of adjoining mol-ecules.

| S-EPMC3009097 | biostudies-literature

[2-Formyl-4-methyl-6-({2-[2-(4-nitro-benzyl-amino)-ethyl-amino]-ethyl-imino}-meth-yl)phenolato]nickel(II) perchlorate.

Project description:In the unsymmetrical title complex, [Ni(C(20)H(23)N(4)O(4))]ClO(4), the coordination geometry for the Ni(II) atom can be described as square planar. The aromatic rings in the two ligands are almost vertical, with a dihedral angle of 85.3°. In the crystal, cations and anions are linked by weak C(N)-H?O hydrogen bonding.

| S-EPMC3379101 | biostudies-literature

4-[(4-Methyl-benz-yl)amino]-3-[(4-methyl-benz-yl)imino-meth-yl]-2H-chromen-2-one.

Project description:The title compound, C(26)H(24)N(2)O(2), was prepared from the reaction of 4-chloro-3-formyl-coumarin with p-methyl-benzyl-amine. Even though there are no strong and specific inter-actions in the crystal structure, the translationally related mol-ecules form chains along the b axis. The coumarin moieties are stacked through ?-? inter-actions [centroid-centroid distance = 3.5275?(7)?Å], forming layers perpendicular to the stacking direction.

| S-EPMC3009000 | biostudies-literature

2-[(4-Meth-oxy-benz-yl)imino-meth-yl]phenol.

Project description:In the title Schiff base compound, C(15)H(15)NO(2), prepared from 4-meth-oxy-benzyl-amine and salicyl-aldehyde, an intra-molecular O-H?N hydrogen bonds influences the mol-ecular conformation; the two aromatic rings form a dihedral angle of 73.5?(1)°. In the crystal, weak inter-molecular C-H?O inter-actions link the mol-ecules into chains propagating in [010].

| S-EPMC3011435 | biostudies-literature

Crystal structure of (E)-5-benz-yloxy-2-{[(4-nitro-phen-yl)imino]-meth-yl}phenol.

Project description:In the title compound, C20H16N2O4, the mol-ecule adopts an E conformation about the N=C bond. There is an intra-molecular O-H⋯N hydrogen bond forming an S(6) ring motif. The nitro-benzene and benz-yloxy rings are inclined to the central benzene ring by 4.34 (10) and 27.66 (11)°, respectively, and to one another by 31.40 (12)°. In the crystal, mol-ecules are linked via C-H⋯O hydrogen bonds, forming zigzag chains along [001]. Within the chains there are C-H⋯π inter-actions present. The chains are linked via π-π inter-actions [inter-centroid distance = 3.7048 (15) Å], forming slabs parallel to the bc plane.

| S-EPMC4719944 | biostudies-literature

(E)-1-[(2-Amino-5-nitro-phen-yl)iminio-meth-yl]naphthalen-2-olate.

Project description:The title Schiff base compound, C(17)H(13)N(3)O(3), crystallizes in a zwitterionic form and exists in a trans configuration about the C=N bond. The mol-ecule is slightly twisted, the dihedral angle between the benzene ring and naphthalene ring system being 10.80?(9)°. The nitro group is twisted relative to the plane of the benzene ring [dihedral angle = 8.88?(12)°]. Bifurcated intra-molecular N-H?N and N-H?O hydrogen bonds formed between iminium groups and amine N atoms and naphthalen-2-olate O atoms generate S(5) and S(6) ring motifs, respectively. In the crystal, neighbouring zwitterions are linked through weak C-H?O inter-actions, giving rise to screw chains along [010]. Mol-ecules in these chains are linked to those of an adjacent chains through N-H?O hydrogen bonds and weak C-H?O inter-actions, forming sheets parallel to the ac plane. O?C [2.895?(3)?Å] short contacts and ?-? inter-actions [centroid-centroid distance = 3.8249?(19)?Å] are also observed.

| S-EPMC2979134 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data