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[2-Formyl-4-methyl-6-({2-[2-(4-nitro-benzyl-amino)-ethyl-amino]-ethyl-imino}-meth-yl)phenolato]nickel(II) perchlorate.

ABSTRACT: In the unsymmetrical title complex, [Ni(C(20)H(23)N(4)O(4))]ClO(4), the coordination geometry for the Ni(II) atom can be described as square planar. The aromatic rings in the two ligands are almost vertical, with a dihedral angle of 85.3°. In the crystal, cations and anions are linked by weak C(N)-H?O hydrogen bonding.

SUBMITTER: Wang Y

PROVIDER: S-EPMC3379101 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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[2-Formyl-4-methyl-6-({2-[2-(4-nitro-benzyl-amino)-ethyl-amino]-ethyl-imino}-meth-yl)phenolato]nickel(II) perchlorate.

Wang Yang Y Mao Jia-Wei JW Song Hui-Ting HT Zhou Hong H

Acta crystallographica. Section E, Structure reports online 20120512 Pt 6

In the unsymmetrical title complex, [Ni(C(20)H(23)N(4)O(4))]ClO(4), the coordination geometry for the Ni(II) atom can be described as square planar. The aromatic rings in the two ligands are almost vertical, with a dihedral angle of 85.3°. In the crystal, cations and anions are linked by weak C(N)-H⋯O hydrogen bonding. ...[more]

PMID: 22719322

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Bis[2,4-dichloro-6-(ethyl-imino-meth-yl)phenolato-κN,O]nickel(II).

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| S-EPMC3247532 | biostudies-literature

Bis[2-(benzyl-amino)-pyridine-κN]bis-(2-formyl-phenolato-κO,O')nickel(II).

Project description:In the title complex, [Ni(C(7)H(5)O(2))(2)(C(12)H(12)N(2))(2)], the Ni(II) atom lies on a center of inversion and is coordinated in an octa-hedral geometry by two 2-(benzyl-amino)-pyridine (2-BAP) and two 2-formyl-phenolate ligands with the O-atom donors in the equatorial plane and the pyridine N atoms in axial positions. There are hydrogen-bonding inter-actions between the secondary amine H atom and the phenolate O atom, as well as C-H⋯O inter-actions, which result in the dihedral angle between the aromatic phenyl ring of the 2-formyl-phenolate moiety and the pyridine ring being 80.23 (4)°. In the packing, there are both C-H⋯π inter-actions, which link the mol-ecules into chains along the b axis, and offset π-π inter-actions involving both the pyridine and phenyl rings of the 2-BAP ligands [centroid-centroid distances = 4.0100 (8) Å for the pyridine rings and 3.6601 (8) and 4.8561 (8) Å for the phenyl rings].

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